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52 results about "Methylmercury" patented technology

Methylmercury (sometimes methyl mercury) is an organometallic cation with the formula [CH₃Hg]⁺. It is the major source of organic mercury for all humans. It is a bioaccumulative environmental toxicant.

Compound biochar-based slow-release fertilizer and application method thereof

The invention discloses compound biochar-based slow-release fertilizer and an application method thereof and mainly relates to the field of biochar-based fertilizer. A preparation method of the compound bio-carbon-based slow-release fertilizer comprises mixing agricultural rice straws and wood shavings, preparing char, adding sodium selenite into the char to obtain biochar, mixing pig manure and chicken manure, carrying out fermentation on the pig manure and chicken manure, carrying out metal passivation treatment to obtain manure-based fertilizer, further fermenting the biochar and the manure-based fertilizer, and adding diatomite into the fermentation product for modification to obtain slow release fertilizer granules. In use, preferably, the slow-release fertilizer granules are applied to the field according to a ratio of 256 kg per mu, and a field moisture capacity measured value is kept in a range of 70% to 80% in the whole growth period. The compound biochar-based slow-release fertilizer can meet the demand of nitrogen and phosphorus in the early stage and the whole period of rice seedling, has sufficient and lasting fertilizer effects, prevents the effects of heavy metals, improves the soil environment, inhibits methylmercury, and can produce high-yield good-quality selenium-rich rice.
Owner:BENGBU COLLEGE

Method for measuring methyl mercury and ethyl mercury in animal flesh

The invention discloses a method for measuring methyl mercury and ethyl mercury in animal flesh. The method is characterized by comprising the following steps of: pretreating an animal flesh sample; performing microwave-assisted extraction; analyzing through a liquid chromatography-atomic fluorescence combined instrument; and finally, collecting and processing the data by using a data processor, and measuring the content of methyl mercury and ethyl mercury in fish flesh. The microwave-assisted extraction and high performance liquid chromatography-atomic fluorescence spectroscopy (HPLC-AFS) method are simultaneously applied to detecting the methyl mercury and ethyl mercury in animal flesh, and an extraction process is optimized; according to selection and concentration control of mobile phase in chromatographic analysis and reasonable control on concentration of hydrochloric acid in atomic fluorescence analysis, selection of reducing agents and lamp current, the process flow is simplified, the content of methyl mercury and ethyl mercury in the animal flesh can be rapidly and simply measured, and the detection method is simple and fast in measurement and high in stability and has the characteristics of high measurement sensitivity, high accuracy and high interference resistance.
Owner:ANIMAL & PLANT & FOOD INSPECTION CENT OF TIANJIN ENTRY EXIT INSPECTION & QUARANTINE BUREAU +1

Novel sulfhydrylization graphene oxide and iron and manganese oxide composite material for removing methylmercury in water body and preparation method

A preparation method of a novel sulfhydrylization graphene oxide and iron and manganese oxide composite material is simple and convenient. The method comprises the steps that a ferrous sulfate solution and a potassium permanganate solution are added into a graphene oxide suspension in sequence, mixing is conducted to be uniform, the pH is adjusted to be 7.5, stirring and standing are conducted, water washing is conducted till the mixture is neutral, and after freeze drying is conducted, graphene oxide and iron and manganese oxide composite material powder is obtained; the powder is cleaned with ethyl alcohol, ultrasonic dispersion is conducted for 1 h in methylbenzene, after cleaning is conducted with ethyl alcohol, the treated powder is dispersed in a 2% 3-mercaptopropyltrimethoxysilane (95% ethyl alcohol) solution, stirring is conducted for 6 h, the pH is adjusted to be 9.5 with ammonia water, stirring is conducted for 24 h, water washing and freeze drying are conducted, and sulfhydrylization graphene oxide and iron and manganese oxide composite material powder is obtained. Graphene oxide is combined with iron and manganese oxides, agglomeration of the iron and manganese oxides is blocked, and the removal effect of methylmercury in water is significantly improved by means of introduction of a sulfhydryl group. The preparation method of the novel sulfhydrylization graphene oxide and iron and manganese oxide composite material has the advantages of being simple in process, stable in effect, wide in application range, environmentally friendly, high in selectivity and the like.
Owner:NANKAI UNIV

Method of determining residual quantity of methylmercury in aquatic products

The invention relates to a method of determining a residual quantity of methylmercury in aquatic products. The method comprises mixedly extracting samples by a given volume of hydrochloric acid of a certain concentration and a sodium chloride solution, extracting with toluene, stripping with an L-cysteine ??solution, deriving with a given volume of derivative agents of two concentrations, pre-treating with n-hexane extraction, measuring the methylmercury by using a gas chromatography-mass spectrometry, wherein a temperature of an introduction port of the gas chromatography is set to be 250-300 DEG C, a carrying gas is set as a constant voltage mode, a nonpolar chromatographic column is selected and an interface temperature is 260-300 DEG C, passing the pre-treated sample through the gas chromatography and then into the chromatographic column, then heating, separating the sample in the chromatographic column, then entering into the mass spectrometry, determining nature of the sample according to a retention time of object compounds, characteristic ions and an abundance ratio, and determining an amount of the sample by an external-standard peak-area method. The method provided by the invention has advantages of accurate analysis method, good selectivity, high sensitivity and small interference.
Owner:谱尼测试集团股份有限公司

Optical-Based Monitoring And Characterization Of Natural Water

The invention is directed towards a method and system for optically-based monitoring of chemicals of potential concern (COPCs), including mercury (Hg), methyl mercury (MeHg), and polychlorinated biphenyls (PCBs). It employs a multi-parameter statistical analysis model, such as partial least square regression (PLS regression), to identify combinations of predictors (e.g., optical, water quality, and physical properties) that have large covariance with the response values. The predictive model is validated against analytic samples from laboratories. The steps in the method are repeated until predictors, or parameters are selected that avoid over-fitting and which yield physically-based results.
Owner:INTEGRAL CONSULTING INC

Methylmercury ion imprinted magnetic microsphere, and preparation method and application thereof

InactiveCN104926990AEnrichment does not affectFast separation and enrichment speedOther chemical processesWater contaminantsMethylmercurySpecific adsorption
The invention discloses a methylmercury ion imprinted magnetic microsphere, and a preparation method and application thereof. The methylmercury ion imprinted magnetic microsphere is an ion imprinted polymer prepared by synthesizing methylmercury ion physical structure three-dimensional holes in the surface of a ferroferric oxide magnetic microsphere. According to the characteristics that the ion imprinted polymer with the methylmercury ion structure three-dimensional holes has high specific adsorption capacity to methylmercury ions, and ferroferric oxide magnetic microspheres can be quickly collected and separated through magnet, specific, rapid and high-expansion preconcentration and separation of ultra-trace methylmercury in water can be realized.
Owner:FUZHOU UNIV

Measuring method of methyl mercury and ethyl mercury

The invention belongs to the field of heavy metal detection, and relates to a measuring method of methyl mercury and ethyl mercury. According to the measuring method, chitosan is taken as a raw material to prepare aminothiourea modified magnetic chitosan (AT-MCS), MSPE is adopted, aminothiourea modified magnetic chitosan (AT-MCS) is taken as a solid phase extracting material, high performance liquid chromatography and atomic fluorescen spectrometry method are combined and adopted to measure methyl mercury and ethyl mercury in environmental water samples, and a morphological analysis method of methyl mercury and ethyl mercury in environmental water samples is established. Operation of the measuring method is simple and convenient; analysis time is shortened greatly; analysis cost is reduced greatly; average recovery rate ranges from 83.4 to 106.0%; the relative standard deviation ranges from 1.61 to 9.83%; extraction effect is excellent; analysis results are accurate; reproducibility is high; the raw materials are cheap and easily available; material preparation process is simple; reaction conditions are mild; and the measuring method is friendly to the environment.
Owner:QINGDAO TECHNOLOGICAL UNIVERSITY

Thermal desorption and sampling device for methyl mercury

InactiveCN104713966ASimplified thermal analysisSimplify operabilityComponent separationMethylmercuryTenax
The invention discloses a thermal desorption and sampling device for methyl mercury. The thermal desorption and sampling device comprises a flow meter and a thermal desorption device, wherein the thermal desorption device comprises a heating coil, a heating power supply, a heating switch and a heating power supply and voltage regulator; when an experiment for determining the content of the methyl mercury is carried out, an argon bottle is firstly opened; argon enters the lower end of the flow meter through a PFA gas pipeline, then flows out from the upper end of the flow meter, and enters a methyl mercury-enriched Tenax adsorption pipe through the PFA gas pipeline; and the heating coil sleeves the adsorption pipe. According to the thermal desorption and sampling device, carrier gas flow control and heating desorption devices are integrated; the thermal desorption and sampling device is simple in structure and convenient to operate; thermal desorption and sampling operation on the methyl mercury are greatly simplified; experiment efficiency is improved; and compared with devices with the similar functions, the thermal desorption and sampling device is extremely low in construction cost.
Owner:HENAN POLYTECHNIC UNIV

Ionic imprinting material for enriching ultratrace methyl mercury in water body

The invention discloses an ionic imprinting material for enriching ultratrace methyl mercury in a water body and a preparation method and application of the ionic imprinting material. A silicon dioxide microsphere serving as a carrier, methyl mercury chloride and pyrrolidinecarbodith which serve as templates, methacrylic acid serving as a functional monomer, TMPTMA serving as a crosslinking agent and azodiisobutyronitrile serving as an initiator are synthesized to form a silicon dioxide microsphere, on the surface of which a three-dimensional cavity ionic imprinting polymer with a methyl mercury ion structure is arranged. The ionic imprinting material has the advantages of short enrichment time, simplicity in operation, high specificity, high enrichment capacity, low cost and the like and can be used for quickly pre-enriching and separating ultratrace methyl mercury ions in various water samples.
Owner:FUZHOU UNIV

Detection method of trace methylmercury in alga

The invention provides a detection method of trace methylmercury in alga. The detection method comprises the following steps: (1) ultrasonic extraction of methylmercury; (2) drawing of a standard curve; (3) measurement of the content of methylmercury in a standard solution and a sample solution by adopting the flame atomic absorption spectrometry. The content of trace methylmercury is measured by the combination of the ultrasonic extraction and the flame atomic absorption spectrometry, the detection range is wide, methylmercury with the concentration of 0-4 mg / L can be detected, and the detection method has relatively high accuracy, besides, is convenient, fast, simple and safe in operation, and is suitable for industrial application.
Owner:DONGCHEN LEADER TESTING

Method for determining content of methylmercury in fish oil

The invention discloses a method for determining a content of methylmercury in fish oil, which comprises extracting a sample, performing chromatographic analysis, performing atomic fluorescence analysis, performing data acquisition on intensities of fluorescence emitted from mercury atoms by data processing software, and listing the collected data to conveniently and accurately detect the content of methylmercury in the fish oil. The invention has advantages that it simultaneously employs the chromatographic analysis and atomic fluorescence analysis, and carries out selection of a mobile phase, and control of the concentration and flow rate of the mobile phase in the chromatographic analysis, and selection of a reductant and an oxidant and control of the lamp current and carrier gas in the atomic fluorescence analysis, thus the content of methylmercury in the fish oil is determined rapidly and conveniently. In addition, the method has low reagent consumption, short analysis period, good stability and high accuracy, and is very practical.
Owner:舟山出入境检验检疫局综合技术服务中心

Mercury methylation genes in bacteria and archaea

Two genes required for this mercury methylation have been identified in bacteria and archaea. These genes are the hgcA gene and hgcB, a corrinoid protein that facilitates methyl group transfer to Hg, and a corrinoid protein-associated ferredoxin with two [4Fe-4S] binding motifs involved in generating cob(I)almin, respectively. The invention provides nucleic acid probes and primers for detecting methylmercury and or for assessing mercury methylation potential in environmental, clinical and other samples. The invention also provides antibodies against these proteins, antibodies against these proteins, methods of using the antibodies and methods of biocatalysis.
Owner:UT BATTELLE LLC

Photoacoustic imaging probe, and preparation method and application thereof

The invention provides a photoacoustic imaging probe, and a preparation method and application thereof. According to the invention, liposome and a cyanine dye are subjected to self-assembling to formthe water-soluble nanoprobe, wherein the cyanine dye has specific response to methylmercury. When a solution contains MeHg<+>, the nanoprobe promotes cyclization through mercury so as to form LP-hCy7', results in a decrease in the intensity of an absorption peak at a wavelength of 690 nm and an increase in the intensity of an absorption peak at a wavelength of 860 nm, and correspondingly leads toreduction in photoacoustic signals at the wavelength of 690 nm and substantial strengthening of signals at the wavelength of 860 nm. The content of MeHg<+> in a biological sample can be detected through photoacoustic imaging of a living body and the PA signal ratio of the LP-hCy7 nanoprobe at the wavelengths of 860 nm and 690 nm. The photoacoustic imaging probe is simple in structure; and the preparation method does not need complicated and expensive equipment, and is simple in process, convenient to operate and easy to realize industrial production.
Owner:SHENZHEN UNIV

DGT fixing membrane for methylmercury and metal mercury ions in sediment, and preparation method thereof, DGT apparatus and eluent

The invention discloses a DGT fixing membrane for methylmercury and metal mercury ions in sediment, and a preparation method thereof, a DGT apparatus and an eluent, wherein the fixing membrane is formed by carrying out film forming and gelation on the mixed liquid of polyacrylamide, zirconium hydroxide hydrate and an isothiourea functionalized macroporous cross-linked polystyrene resin. Accordingto the present invention, with the fixing membrane, the mercury metal in the wetland soil sediment can be efficiently and quickly adsorbed and eluted so as to determine the mercury content.
Owner:南京智感环境科技有限公司

Application of graphite-like carbon nitride nano material as electrochemical modified electrode material in detection of methyl mercury

The invention discloses an application of a graphite-like carbon nitride nano material as an electrochemical modified electrode material in detection of methyl mercury. During application, the detection method comprises the steps of putting a to-be-used nano composite material into deionized water to form a suspension; fully coating the outer surface of the electrode, and air-drying to obtain an electrochemically modified electrode, taking the electrochemically modified electrode as a working electrode in a three-electrode system of an electrochemical workstation, and detecting the concentration of the methyl mercury ions in the to-be-detected liquid under the power-on state of the three-electrode system. According to the invention, the dispersibility and high surface area can be provided,the electronic band gap is adjusted, the ionic conductivity is improved, the defects of low sensitivity and high detection limit of the existing electrochemical detection technology on methyl mercuryion detection are improved, and the detection limit is far lower than a standard value specified by WHO.
Owner:HEFEI UNIV OF TECH

Fluorescent probe kit for detecting total mercury and methyl mercury in water and detection method

InactiveCN111537482AGuaranteed specificity of assay selectionAvoid fluorescent responseFluorescence/phosphorescenceLuminescent compositionsFluoProbesMercuric ion
The invention relates to the technical field of total mercury and methyl mercury detection, in particular to a fluorescent probe kit for detecting total mercury and methyl mercury in water and a detection method. The fluorescent probe kit comprises a buffer solution reagent, a probe solution and a DNA reagent. The buffer solution is an acetonitrile-HEPES buffer solution, the concentration of the buffer solution is 8-12 mM, and the pH value of the buffer solution is 6-8; a pyridine structure, four naphthalimide fluorophores and an oxygen-containing long-chain structure are contained in a probemolecule; the base sequence of the DNA is 5-TTGTTTGTTGGCCCCCCTTCTTTCTT-3'. Free rotation of four naphthalimide fluorophores in the probe can annihilate excitation energy in a non-radiative manner, sothat the probe cannot be excited to emit strong fluorescence in a solution; when mercury ions or methyl mercury exists in the solution, mercury ions or methyl mercury can be coordinated and combined with the probe to limit the rotation of a naphthalimide group, a probe solution can be excited by ultraviolet light to generate strong fluorescence, and DNA can be used as a mercury ion masking agent for qualitative detection of methyl mercury when the mercury ions and the methyl mercury exist at the same time.
Owner:DATANG ENVIRONMENT IND GRP

Method for testing methyl mercury and ethyl mercury in aquatic feed

ActiveCN109187789AEliminate distractionsAchieving Simultaneous ExtractionComponent separationSpike recoveryMethylmercury
The invention discloses a method for testing the methyl mercury and the ethyl mercury in the aquatic feed. The method comprises the following steps of: using simultaneous distillation extraction method to simultaneously collect and extract samples, and water back extract; then performing a derivative reaction by using the sodium(tetra-n-propyl)borate as a derivatization reagent; finally, testing the methyl mercury and the ethyl mercury in the aquatic feed by using a full automatic alkyl mercury tester. According to the method for testing the methyl mercury and the ethyl mercury in the aquaticfeed, the method detection limit of the methyl mercury is 2mu / kg, the quantification limit is 6mu / kg, the relative standard deviation is 4.58%, and the average spike recovery is between 90.6% and 97.3%; the method detection limit of ethyl mercury is 4mu / kg, the quantification limit is 11mu / kg, the relative standard deviation is 5.19%, and the average recovery rate is between 89.2% and 96.7%. The sensitivity is high, the repeatability is good, the accuracy is good, and particularly the method detection limit and the quantitation limit are especially suitable for testing the methyl mercury and the ethyl mercury in the aquatic feed.
Owner:INSPECTION AND QUARANTINE TECHNOLOGY CENTER ZHONGSHAN ENTRY EXIT INSPECTION AND QUARANTINE

Device for removing methyl mercury in low-temperature seawater and manufacturing method thereof

The invention provides a device for removing methyl mercury in low-temperature seawater and a manufacturing method of the device. The device is of a polyhedral structure. The polyhedral structure is provided with a polyhedral frame; wherein a polyhedral agarose gel is arranged in the polyhedral frame; a hole is formed in the center of each surface of the agarose gel and is filled with 3-mercaptopropyl functionalized silica gel; each surface of the agarose gel is covered with a nitrocellulose membrane covering the surface of the 3-mercaptopropyl functionalized silica gel and the surface of theagarose gel, and the thickness of the nitrocellulose membrane is 0.45 [mu]m. The device is not influenced by external temperature and heavy metal types, is simple in overall structure, convenient to use, high in seawater purification degree and good in removal effect of methyl mercury in low-temperature seawater, and can reduce the content of methyl mercury in the low-temperature seawater.
Owner:SHANGHAI OCEAN UNIV

Treatment method for methyl mercury polluted water

The invention discloses a treatment method for methyl mercury polluted water. The treatment method comprises the following steps: introducing water containing methyl mercury into a cationic resin exchanger, and stopping exchanging when the concentration of methyl mercury in a water solution flowing from the cationic resin exchanger is greater than 0.00005mg / L; taking out cationic resin, utilizing a saturated sodium chloride mixed liquor of 8-12% stannous chloride as regenerated liquid, and performing regeneration under a mixing condition, wherein the ratio of the regenerated liquid to the resin is (1-2) to 5, the mixing time is 40-60 minutes, and the temperature is 40-45 DEG C; separating the resin from mercury-containing liquid after regeneration is ended, returning the regenerated resin to the resin exchanger to recycle, and feeding the mercury-containing liquid into a sedimentation basin; adjusting the pH of the obtained mercury-containing liquid to be greater than 10 by using sodium hydroxide, and filtering the mercury-containing liquid to obtain mercury-containing sediments; smelting the mercury-containing sediments by using a smelting furnace at high temperature of 560 DEG C, recovering mercury vapor, and condensing the vapor, so as to obtain a metal mercury product. By adopting the treatment method, methyl mercury pollution in water can be removed, and the methyl mercury can be converted into metal mercury to recycle.
Owner:何华

Fluorescent probe for rapidly identifying mercury and methyl mercury as well as preparation method and application of fluorescent probe

The invention belongs to the field of analytical chemistry, and relates to a fluorescent probe for rapidly identifying mercury and methyl mercury as well as a preparation method and application of thefluorescent probe. The structural formula of the fluorescent probe is shown in the specification. According to the prepared fluorescent probe, under the condition of not adding any other additional material, the detection sensitivity is improved, the additional material is prevented from being added, the consumption of the additional material is reduced, and the error source in detection is reduced; imaging of an object to be detected in living cells and zebra fish bodies is successfully detected in the detection process, the fluorescent probe is suitable for real-time monitoring and distinguishing of the living bodies such as the cells and the zebra fish bodies, and the method cannot be achieved in previous methods. Implementation of imaging plays a great role in promoting deep researchof distinguishing mercury and methyl mercury.
Owner:BEIJING NORMAL UNIVERSITY

Method for extracting and condensing methyl mercury from gasoline by using mercapto cotton

The invention relates to a method for direct extracting and concentrating methylmercury from petrol by sulfhydreyl cotton fibers, which belongs to the field of substance isolation technique and comprises: making the petrol flowing through the sulfhydreyl cotton fibers, taking off the sulfhydreyl cotton fibers tube as the petrol flowing out completely, blowing out the remnant petrol using an inner stopper, then eluting the rich methylmercury of sulfhydreyl cotton fibers using chlorhydric acid solution, collecting the chlorhydric acid eluent into a color comparison tube with the plug, sucking the purified petroleum benzene to extract the methylmercury of the eluent, drawing the upper layer benzene liquid after inaction stratification, making the methylmercury gauging by a gas chromatograph.
Owner:NORTHEAST INST OF GEOGRAPHY & AGRIECOLOGY C A S

Fluorescein type ionic liquid, synthetic method thereof and application of fluorescein type ionic liquid in detection of mercury ions or methyl mercury ions

The invention discloses a fluorescein type ionic liquid, a synthesis method thereof and an application of the fluorescein type ionic liquid in mercury ion or methyl mercury ion detection, the chemical formula of the fluorescein type ionic liquid is [Fluo] [P66614] 2, and the structural formula is shown as a formula (I); the ionic liquid with green fluorescence emission is synthesized through a simple ion exchange method, the method is simple in synthesis step, and raw materials are simple and easy to obtain; the designed and synthesized [Fluo] [P66614] 2 fluorescent ionic liquid is high in quantum yield, good in thermal stability and small in environmental pollution; according to the method, the mercury ions and the methyl mercury ions in an actual sample can be qualitatively analyzed and quantitatively detected, and possibility is provided for rapid detection of the mercury ions and the methyl mercury ions in the actual sample;
Owner:ZHEJIANG UNIV OF TECH

Method and device for on-line enrichment and determination of ultra-trace methyl mercury and/or divalent mercury

ActiveCN111257463AReduce usageSimplify enrichment and elution stepsComponent separationMethylmercuryElution
The invention discloses a method and a device for the on-line enrichment and determination of ultra-trace methyl mercury and / or divalent mercury. The method comprises the following steps: modifying and activating an enrichment column; carrying out extraction and enrichment on methyl mercury and / or divalent mercury by utilizing the modified and activated enrichment column; eluting the methyl mercury and / or the divalent mercury enriched on the enrichment column by utilizing eluent; and separating the enriched methyl mercury and / or divalent mercury by using the eluent, and carrying out online ultra-trace determination on the methyl mercury and / or divalent mercury desorbed from the separation column by using a detector. According to the method and the device disclosed by the invention, the enrichment and elution steps are greatly simplified, the use of toxic reagents is reduced, and the green safety of the method is improved while the method and the device are suitable for detecting ultra-trace methyl mercury and divalent mercury; and on the basis of small sample size, a better detection limit effect is achieved. Therefore, the invention provides the method and the device for on-line enrichment and determination of ultra-trace methyl mercury and / or divalent mercury, which are efficient, convenient and good in performance.
Owner:RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI

A method for visual detection of methylmercury based on DNA regulation of gold-amalgam growth

The invention discloses a methyl mercury visual detection method of gold-mercury alloy nanoparticle growth regulation and control based on a DNA template, and belongs to the technical field of heavy metal detection. According to the method, an HT9 DNA nucleic acid template is uniformly mixed with different concentrations of methyl mercury standard solutions, incubation is carried out for 5 minutesafter mixing, a sodium borohydride solution is added to prepare nano seed crystal by reduction, a hydroxylamine hydrochloride solution and a chloroauric acid solution are sequentially added then, a solution color is recorded after fully and uniformly mixing, a standard color card is established, the absorbance of the solution is determined by a microplate reader and corresponds to the concentration of methyl mercury, and a standard work curve is established. Operation is carried out by replacing the methyl mercury standard solution with a marine product extracting solution, a corresponding solution color is recorded and compared with the standard color card, the absorbance of the solution is detected and substituted into the standard curve, so that organic mercury in a marine product is detected. The method is simple, sensitive, stable and high in anti-interference capability, does not need heating, can be used to complete detection within 30 minutes, and is low in detection cost.
Owner:FUJIAN AGRI & FORESTRY UNIV +1

Method and device for removing methyl mercury in sewage by using ternary composite nano material

ActiveCN111847625ARapid Catalytic Degradation TreatmentEfficient catalytic degradation treatmentSpecific water treatment objectivesWater contaminantsOxidative enzymePhotocatalytic degradation
The invention discloses a method and a device for removing methyl mercury in sewage by using a ternary composite nano material. The method comprises the following steps: uniformly mixing the ternary composite nano material with the sewage possibly containing the methyl mercury, thereby catalytically degrading the methyl mercury in the sewage into carbon dioxide, water and amalgam formed on the ternary composite nano material. The device comprises a sewage storage mechanism, a ternary composite nano material storage mechanism, a degradation generation mechanism, a ternary composite nano material recovery mechanism and a degradation monitoring mechanism. According to the method, the methyl mercury can be removed only by utilizing the oxidase property of the ternary composite nano material without light and no microorganisms; compared with methods for removing the methyl mercury through biodegradation, photocatalytic degradation and the like, the method has the advantages of being simpleand convenient in removal process, high in removal efficiency, high in removal speed, low in removal cost and the like, meanwhile, mercury ions entering the water body again are not generated, secondary pollution is avoided, and the methyl mercury in the sewage can be completely removed.
Owner:JILIN UNIV

Fluorescent ion imprinted sensor and application thereof in methyl mercury ion detection

ActiveCN102585281BTo achieve specific identificationEasy to makeFluorescence/phosphorescenceFunctional monomerCross linker
The invention provides an ion imprinted fluorescent sensor for selectively detecting methyl mercury ions and a preparation method for the ion imprinted fluorescent sensor. The sensor is prepared by the following three processes of: (1) forming a pre-copolymer by using the methyl mercury ions, a functional monomer and a fluorescent material through coordination; (2) adding a cross linker and an initiator, and performing initiated polymerization under proper conditions by using a microporous membrane as a supporting medium to immobilize template molecules in the polymer in a complementary spatial structure form; and (3) removing the template molecules from the polymer in an acid or ethylene diamine tetraacetic acid (EDTA) eluting mode, leaving specific holes, and thus obtaining the fluorescent methyl mercury ion imprinted composite membrane sensor. The obtained imprinted composite membrane shows high selectivity and sensitivity to methyl mercury ions, and can be reused for multiple times; and the fluorescent sensor is easy and fast to prepare, and can be used for selective detection of the methyl mercury ions in samples of environment and the like.
Owner:ZHEJIANG UNIV OF TECH

Method for detecting low-concentration methyl mercury

The invention relates to a method for detecting low-concentration methyl mercury. The method specifically comprises the following steps: firstly, adding an ammonium sulfide solution in the concentration of 5-10 mol / L into a water sample to be detected, sequentially carrying out static settlement and centrifugation according to the volume ratio of the water sample to the ammonium sulfide solution of 1: 0.02, then adding hydrochloric acid and potassium borohydride into the water sample to be detected, carrying out oscillation extraction at 45-70 DEG C by adopting an Au coated solid-phase microextraction sampler, and finally, transferring the extracted solid-phase micro-extraction sampler into a mercury measuring instrument, and measuring methyl mercury. According to the method disclosed by the invention, interference of mercury ions in detection is effectively removed, the enrichment efficiency of methyl mercury is improved, the detection of methyl mercury with lower concentration in a water body is realized, the detection limit is 0.02 mu g / L, a good linear relation is realized in a range of 0.2-10 mu g / L, and the detection method has excellent selectivity on methyl mercury.
Owner:CHONGQING THREE GORGES UNIV

A fluorescent probe for quickly identifying mercury and methylmercury and its preparation method and application

The invention belongs to the field of analytical chemistry, and relates to a fluorescent probe for quickly identifying mercury and methylmercury, a preparation method and an application thereof. The structural formula of the fluorescent probe is as follows:. The fluorescent probe prepared by the present invention improves the detection sensitivity without adding any other additional materials, and avoids the addition of additional materials, reduces the consumption of additional materials and reduces the source of errors in the detection; in the detection The imaging of the analyte in living cells and zebrafish has been successfully detected, and it is suitable for real-time monitoring and differentiation of cells and zebrafish in vivo. This method has not been able to do it in the previous method. The realization of imaging has greatly promoted the in-depth study of distinguishing mercury from methylmercury.
Owner:BEIJING NORMAL UNIVERSITY

A kind of detection method of methylmercury ion

The invention discloses a method for detecting methyl mercury ions. This method combines the advantages of nanomaterials and utilizes methylmercury ions to block the formation of silver nanoparticles using fluorescein-labeled T-rich DNA as a template to achieve fluorescence retention, so as to detect methylmercury ions. The method for detecting methyl mercury ions of the present invention is convenient, simple and fast, does not need expensive instruments, has low cost, and has high detection sensitivity, and can achieve high response to methyl mercury ions while better overcoming the interference of divalent mercury ions. good practical application prospects.
Owner:HUNAN UNIV

Transgened-tobacco for degrading organic mercury pollution

InactiveCN100398656CHigh resistance to organic mercuryAltered resistance against organomercuryContaminated soil reclamationFermentationMethylmercuryNicotiana tabacum
The invention was involved in organic mercury lyase merB gene, which was expressed in plants. The gene was achieved by changing the sequence of merB catalysed methyl mercury into ion mercury in the bacteria.Then modified merB gene was transferred into plants so that modified gene plants with strong resistance to organic mercury was achieved. The modified gene plants could be used to degrade pollution of organic mercury in soils.
Owner:SHANGHAI INST OF BIOLOGICAL SCI CHINESE ACAD OF SCI
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