The invention relates to a non-ionic self-emulsifying
solid epoxy resin and a preparation method of the
emulsion of the resin, belonging to the
coating material chemical manufacturing industry. The preparation method adopts a 'two-
step method' principle during preparation: step one: under the protection of
nitrogen, the reaction of 5 to 25 percent of low-molecular weight
epoxy resin, 40 to 70 percent of polyether
alcohol, 1 to 10 percent of
solvent and 0.01 to 0.1 percent of catalyst is carried out at 90 to 150 DEG C, and then a constant temperature is kept for 2 to 7 hours before intermediate is obtained through the
vacuum distillation of the
solvent; step two: 10 to 25 percent of intermediate, 40 to 70 percent of low-molecular weight
epoxy resin, 5 to 25 percent of
bisphenol A and 0.02 to 0.1 percent of catalyst are heated up to 120 to 180 DEG C, and then a constant temperature is kept for 1 to 3 hours before non-ionic self-emulsifying
solid epoxy resin with
medium molecular weight and high molecular weight is obtained; and finally, at the temperature of 20 to 90 DEG C,
distilled water is dripped in to dilute the solution to a degree with
solid content
ranging between 30 and 80 percent of through violent stirring, thereby obtaining non-ionic self-emulsifying solid epoxy resin
emulsion. The preparation method has convenient operation, stable manufacturing technique,
energy conservation and moderate preparation process. Moreover, the water-based epoxy
emulsion is exquisite and has uniform particle
diameter and high product quality.