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131results about How to "Improved thermal dimensional stability" patented technology

Composite nanofiber lithium battery diaphragm and making method thereof

The invention relates to a composite nanofiber lithium battery diaphragm and a making method thereof. The composite nanofiber lithium battery diaphragm is obtained by compounding at least one layer of an aramid 1313 nanofiber film containing nanoparticles with at least one layer of a low-melting-point polymer nanofiber film containing nanoparticles, and nanofibers in the fiber films containing nanoparticles are mutually interlaced and are bonded and connected with each other at interlaced points. The aperture range and the pore closing temperature of the surface layer of the fibers in the composite nanofiber lithium battery diaphragm are 100-400nm and 130-170DEG C respectively, the fiber film does not shrink after the pore closure, the heat shrinkage is less than 2% after the fiber film is heated at 250DEG C for 1h, and the tensile strength is 100-1000MPa, so the composite nanofiber lithium battery diaphragm has the characteristics of heat closing effect, good heat dimension stability and high strength. The making method has the advantages of simple process and low cost, and the obtained composite nanofiber lithium battery diaphragm has a wide application prospect in energy storage fields of supercapacitors, sodium ion batteries and the like.
Owner:DONGHUA UNIV

Composite diaphragm, preparation method thereof and lithium ion battery

ActiveCN104088155AGood thermal dimensional stabilityImprove safety and charge and discharge performanceFibre typesSecondary cellsMethyl methacrylateSilane coupling
The invention relates to a composite diaphragm. The composite diaphragm comprises a non-woven fabric-organic polymer composite base material, and a composite gel compounded with the non-woven fabric-organic polymer composite base material, wherein the non-woven fabric-organic polymer composite base material comprises a non-woven fabric and a cross-linked polymer, and the cross-linked polymer is formed by copolymerization of a polymer monomer containing alkenyl and alkoxy silane containing alkenyl in the presence of a catalyst and a cross-linking agent; the composite gel comprises a gel polymer and inorganic modified nano powder, and the inorganic modified nano-powder comprises a polymer formed by copolymerization of methyl methacrylate and a silane coupling agent containing C=C groups, and further comprises a nano-sol connected with the alkoxy silane by virtue of condensation reaction. The invention also relates to a preparation method of the composite diaphragm and a lithium ion battery.
Owner:JIANGSU HUADONG INST OF LI ION BATTERY +1

Preparation method for polyimide with cross-linked structure and application of polyimide nanofiber membrane in lithium battery diaphragm

The invention provides a preparation method for a polyimide nanofiber membrane with a cross-linked structure and application of the polyimide nanofiber membrane in a lithium battery diaphragm, belonging to the field of high polymer materials. The preparation method comprises the following steps: subjecting a polyamide acid solution to electrostatic spinning to prepare a polyamide acid nanofiber membrane; etching the polyamide acid nanofiber membrane in an aqueous ammonia solution with a pH value of 8 to 10 for 60 s to form the cross-linked structure; and carrying out washing, drying and imidization at a temperature of 300 DEG C so as to prepare the polyimide nanofiber membrane. The lithium ion battery diaphragm provided by the invention has high mechanical properties, heat stability, high porosity and excellent electrochemical performance. The battery diaphragm has the cross-linked structure and high mechanical properties, thereby overcoming the problems of low strength and an over-open pore structure of a nonwoven polyimide nanofiber membrane. Meanwhile, the diaphragm has porosity of about 80% and can resist a high temperature of 300 DEG C without any deformation, thereby overcoming the disadvantages of low porosity and poor temperature resistance of a polyolefin microporous diaphragm. In particular, the diaphragm provided in the invention has specific capacity substantially better than that of the traditional polyolefin microporous diaphragm under the conditions of high-rate rapid charging and discharging.
Owner:BEIJING UNIV OF CHEM TECH

Filter medium

InactiveCN1767882AGood dust collection efficiencyLess rise in pressure lossHuman health protectionFiltration separationFinenessFilter material
A filter material containing polyphenylene sulfide fiber satisfies the following characteristics (1) and (2), thereby providing a filter material with excellent dust collection efficiency and high mechanical strength and a composition thereof The bag filter, (1) contains at least 2 layers of fiber mesh, the fiber mesh on the air inflow side contains 50wt% or more heat-resistant fibers with a fiber diameter of less than or equal to 15 μm, and the fiber on the air discharge side The net contains 50wt% or more of heat-resistant fibers with a fiber diameter greater than or equal to 20 μm; (2) contains a fiber net, which contains polyphenylene sulfide short fibers with a fineness in the range of 1 to 3 decitex and a fineness in the range of Short fibers of fluorine-based fibers in the range of 2 to 4 dtex.
Owner:TORAY IND INC

SiO2-PS nuclear shell structure ceramic coating diaphragm and preparation method and application thereof

The invention relates to the technical field of the lithium ion battery diaphragm production, and specifically relates to a SiO2-PS nuclear shell structure ceramic diaphragm coating. A preparation method of the SiO2-PS nuclear shell structure ceramic diaphragm coating comprises the following steps: after modifying the monodispersed nanometer SiO2-particle in-situ grafted gamma-methacryloyloxy trimethoxy silane (MPS) prepared through the St-ber method, coating the monodispersed nanometer modified SiO2 particles by adopting the polyvinyl pyrrolidone ethanol solution and styrene-azodiisobutyronitrile mixed solution, thereby forming the nuclear shell structure with stable combination effect, and preparing the SiO2-PS nuclear shell structure ceramic diaphragm coating slurry; the nuclear shell SiO2-PS composite particle with good dispersibility can be uniformly dispersed in the coating slurry system and cannot produce excessive agglutination, and can form the coating not hindering the polyolefin porous diaphragm gap after being coated on the polyolefin porous diaphragm, and has good combining effect with the polyolefin porous diaphragm, and the membrane has good mechanical performance onthe whole; the diaphragm has stable membrane form under high-temperature state, the SiO2 of the nuclear layer is free from ceramic powder falling and blocking diaphragm duct under the coating of theglass-state polymer when the heat shrinkage phenomenon of the diaphragm caused by the high temperature is effectively blocked, and the security of the lithium ion battery is improved.
Owner:安徽美芯新材料有限公司

Fiber internally-reinforced wood plastic product with high impact resistance, high folding resistance and high size stability and preparation method thereof

The invention discloses a fiber internally-reinforced wood plastic product with high impact resistance, high folding resistance and high size stability and a preparation method thereof. The product is formed through co-extrusion of a core layer and a surface layer; the core layer is composed of core layer polymer resin, fibers, plasticizer, a lubricating agent, antioxygen, core layer stabilizer and an interface modifying agent; the surface layer is composed of surface layer polymer resin, wood flour, surface layer stabilizer, calcium carbonate, a foaming agent, a foaming conditioning agent and plasticization stabilizer. The preparation method includes the steps that 1, surface layer raw materials are mixed to be uniform; 2, melt extrusion granulation is conducted, and surface layer particle materials are obtained; 3, the dried core layer resin is uniformly mixed with other core layer raw materials; 4, melt extrusion granulation is conducted, and core layer particle materials are obtained; 5, the surface layer particle materials and the core layer particle materials are subjected to co-extrusion, and the fiber internally-reinforced wood plastic product is obtained; or, the uniformly mixed surface layer particle materials and core layer particle materials are subjected to co-extrusion, and the fiber internally-reinforced wood plastic product is obtained. The wood plastic product has good impact resistance and bending resistance and is good in heated size stability.
Owner:GUANGDONG KINGFA TECH CO LTD

High-temperature-resistant polymer modified ceramic diaphragm and application thereof

The invention discloses a high-temperature-resistant polymer modified ceramic diaphragm and an application thereof. The high-temperature-resistant polymer modified ceramic diaphragm comprises a porousbase membrane, and at least one surface of the porous base membrane is coated with a ceramic layer; and a high-temperature-resistant polymer layer is arranged on the surface and in the interior of pores of the ceramic layer, in the interior of pores of the porous base membrane, and on the surface not coated with the ceramic layer in an in-situ polymerization manner. The high-temperature-resistantpolymer modified ceramic diaphragm has relatively high thermal stability. Through the in-situ polymerization method of pyrrole, the thiophene and the aniline monomer, a high-temperature-resistant polymer protection layer is formed on the surface and in the interior of pores of the ceramic layer, on the surface of the porous base membrane, and in the pores in an in-situ coating manner, so that theceramic layer, the polymer layer and the base membrane form an organic integrated body; therefore, the thermal size stability of the modified ceramic diaphragm is improved, and the modified ceramic diaphragm does not contract at a high temperature of 200 DEG C; and in addition, relatively high mechanical performance is still kept, positive and negative electrode contact can be effectively obstructed, and the safety performance of the battery can be guaranteed.
Owner:XIAMEN UNIV

Polyimide film with ultralow dielectric loss

The invention provides a polyimide film with ultralow dielectric loss and a preparation method thereof, the polyimide film is capable of being directly adhered to a copper foil, the polyimide film comprises a core layer and a surface layer, or the polyimide film comprises two surface layers and a core layer which is sandwiched between the two surface layers, the dielectric loss factor of the polyimide film at 10GHz test frequency is 0.0030-0.0060, and the dielectric constant is less than 3.0.
Owner:RAYITEK HI TECH FILM CO LTD

Polyester film

Provided is a polyester film which is excellent in heat resistance, chemical resistance, insulating characteristics, dimensional stability at elevated temperatures, and is suitable for use in a variety of fields of application such as those needing a boiling or retort treatment which requires satisfactory levels in toughness, the resistance to pin-holing, the resistance to flexing, the resistance to the breakage of a bag by dropping, impact resistance and the like, those practicing thermal molding or vacuum molding, those of bags for packaging foods containing water or drugs. A polyester film, characterized in that it exhibits an initial modulus of elasticity at least in one direction of 2.5 to 10 GPa, an impact strength of 40 to 10000J / mm, a thermal shrinkage at 150 DEG C at least in one direction of -0.5 to 6 %, a haze of 0.001 to 7 %, and an absolute value of the difference between the thermal shrinkage percentages in the longitudinal direction and in the transverse direction of 1.1 % or less.
Owner:TOYOBO CO LTD

Composite lithium-sulfur battery diaphragm, preparation method thereof and application

InactiveCN107978717AInhibition of the shuttle effectImproved Coulombic efficiency and cycle stabilityCell seperators/membranes/diaphragms/spacersElectro conductivitySolvent
The invention discloses composite lithium-sulfur battery diaphragm, a preparation method thereof and application. The method comprises the steps of impregnating porous substrate membrane into reactionprecursor solution composed of reaction monomers, cross-linking agent, initiator and solvent; and carrying out in situ polymerization and cross-linking reaction under certain condition, thereby acquiring gel electrolyte filled composite lithium-sulfur battery diaphragm with nanoscale pore diameters. According to the lithium-sulfur battery diaphragm, the porous substrate membrane is taken as a framework material, so the good mechanical property and excellent thermal dimension stability are endowed to the diaphragm; the filled gel electrolyte has a great number of lithium conduction functionalgroups, so channels for lithium ions to shuttle are provided, and the problem that the ionic conductivity is relatively low due to reduction of the pore diameters of the diaphragm is avoided; and according to the prepared nanoscale pore diameter composite diaphragm, migration of polysulfide can be inhibited through physical range limitation and chemical absorption effect, so the coulombic efficiency and cycling stability of the lithium-sulfur battery are improved. The composite lithium-sulfur battery diaphragm, the preparation method thereof and the application are simple in technology and high in practicability, are easy to popularize and are beneficial for accelerating industrial application of a lithium-sulfur battery.
Owner:SUN YAT SEN UNIV

Biaxially oriented polyethylene terephthalate film and method for producing same

This film provides a polyethylene terephthalate film whereby dimensional variation in various steps can be reduced, particularly when the film is used as a substrate film for a flexible device, and that is suitable as a substrate film having minimal curl and excellent appropriateness for processing. This biaxially oriented polyethylene terephthalate film has a degree of crystallinity (Xc) of 0.35 to 0.50, the intrinsic viscosity (IV) of the resin constituting the film is 0.66-1.0 dl / g, the coefficient of thermal expansion at a temperature of 50-170° C. in each of the machine direction and transverse direction of the film is 0.29 ppm / ° C., and the degree of thermal shrinkage at 180° C. in each of the machine direction and transverse direction of the film is 0.5%-1.0%.
Owner:TORAY IND INC

Biaxially oriented polyethylene terephthalate film and method for producing same

This film provides a polyethylene terephthalate film whereby dimensional variation in various steps can be reduced, particularly when the film is used as a substrate film for a flexible device, and that is suitable as a substrate film having minimal curl and excellent appropriateness for processing. This biaxially oriented polyethylene terephthalate film has a degree of crystallinity (Xc) of 0.35 to 0.50, the intrinsic viscosity (IV) of the resin constituting the film is 0.66-1.0 dl / g, the coefficient of thermal expansion at a temperature of 50-170 DEG C in each of the longitudinal direction and width direction of the film is 0.29 ppm / DEG C, and the thermal shrinkage at 180 DEG C in each of the longitudinal direction and width direction of the film is 0.5%-1.0%.
Owner:TORAY IND INC
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