The invention discloses a
charcoal amine
sulfur dual-group modification method. The method comprises the following steps that
charcoal is subjected to
nitric acid acidification oxidation, after ultrasonic
concussion is performed for 2-5 h, centrifugal washing is performed till the
charcoal is neutral to obtain oxidized
activated charcoal BC-O; on the basis of the oxidized
activated charcoal BC-O, the proper PH is adjusted, methanal is added under the constant temperature of 40-60 DEG C, ta reaction is performed to 20-50 min,
polyamine substances are added dropwise, a reaction is performed for 4-6 h, and amino modified charcoal BC-N is obtained; cooling is performed to reach the
room temperature, NaOH with the
mass fraction being 40-50% is added,
carbon disulfide is added dropwise to perform a sulfenyl reaction, after dropping is completed, the temperature is increased to 60-80 DEG C, and a reaction is performed for 5-7 h; centrifugal washing is performed, and after
drying, the amine
sulfur dual-group modified charcoal BC-SN is obtained. The prepared modified charcoal has the advantages that surface groups are abundant, the specific surface area is large, and the pore volume is large, and heavy
metal ions are adsorbed and passivated.