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Composite passivant for soil polluted by heavy metal and preparation method

A technology of polluted soil and heavy metals, applied in the restoration of polluted soil, chemical instruments and methods, soil conditioning materials, etc., can solve the problems of unstable cadmium content in rice, reduce soil cadmium bioavailability, and reduce plant absorption, etc. , to achieve the effect of in-situ passivation of heavy metals in soil, improvement of soil tillability, and enhancement of permeability

Active Publication Date: 2012-06-27
INST OF SUBTROPICAL AGRI CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the research results show that the application of lime-like substances is an effective measure to reduce soil cadmium bioavailability and reduce plant uptake, but the effect varies greatly under different soil conditions, types of lime-like substances, dosage and management conditions (Hong et al. , 2007; Tsadilase et al., 2005; Huo Wenrui et al., 1989; Cao Renlin et al., 1992; Tu Naimei et al., 2000; Liao Min et al., 1998)
The research results of Cao Renlin et al. (1992) and Huo Wenrui et al. (1992) showed that on acidic paddy soil, the application of lime can significantly promote the growth and yield of rice and reduce the cadmium content of rice; growth, reduce the yield of rice, and the effect of reducing the cadmium content of rice is very unstable, and even the cadmium content of rice treated with lime is higher than that of the control

Method used

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  • Composite passivant for soil polluted by heavy metal and preparation method
  • Composite passivant for soil polluted by heavy metal and preparation method
  • Composite passivant for soil polluted by heavy metal and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A compound passivator for heavy metals in polluted soil, which is made from the mass fractions of the following three raw materials:

[0031]

[0032]

[0033] A preparation method of a composite passivator for heavy metals in polluted soil, the steps of which are:

[0034] A. Power plant slag preparation: collect waste slag from thermal power plants, pass through a 20-mesh, or 25-mesh, or 30-mesh, or 35-mesh, or 40-mesh sieve through ball milling, and set aside. The waste slag of the thermal power plant, the SiO contained in it 2 Content between 60-70%, CaO+MgO+MnO 2 +Fe 2 o 3 The sum of the four is 15-20%, the content of heavy metal cadmium and lead is ≤5mg / kg in Cd and Pb respectively, and the moisture content is in H 2 O ≤ 1.0%.

[0035] B. Preparation of sepiolite ore powder: choose sepiolite raw ore, pass through a 100-mesh, or 110-mesh, or 120-mesh, or 130-mesh, or 140-mesh sieve through ball milling, and set aside. Described sepiolite raw ore, the co...

Embodiment 2- example 15

[0039] A compound passivator for heavy metals in polluted soil, which is made of the mass fraction of the following raw materials:

[0040] Example

2

3

4

5

6

7

8

9

10

11

12

13

14

15

Power plant slag

54.0

52.5

51.0

49.5

48.0

46.5

45.0

43.5

42.0

40.5

39.0

36.0

34.5

33.0

Sepiolite Mineral Powder

25.0

26.0

27.0

28.0

29.0

30.0

31.0

32.0

33.0

34.0

35.0

37.0

38.0

39.0

quicklime

21.0

21.5

22.0

22.5

23.0

23.5

24.0

24.5

25.0

25.5

26.0

27.0

27.5

28.0

[0041] Its preparation steps are identical with embodiment 1.

[0042] The finished product, which reduces the content range of active ingredients such as silicon oxide, mag...

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Abstract

The invention discloses a composite passivant for soil polluted by heavy metal and a preparation method thereof. The composite passivant is prepared by three raw materials of power plant slags, sepiolite mineral powder and calcined lime in proportion. The preparation method comprises the following steps: A. preparing the power plant slags; B. preparing the sepiolite mineral powder preparation; and C. evenly mixing the raw materials prepared by steps A and B with the calcined lime, wherein the mixture is the composite passivant. By utilizing the composite passivant, the contents of the effective constituents, such as silicon oxide, magnesium oxide, calcium oxide, ferric oxide and the like lowering the soil heavy metal activity is 78.2-90.6% which is calculated by the sum of SiO2, MgO, CaO,MnO2 and Fe2O3; the composite passivant can be widely used in various soils polluted by the heavy metal, especially the soil with visco-weight texture; and by using the composite passivant, the contents of cadmium and lead in a soil active state in the pollutant farmland are lowered by 15.9-48.4% and 26.2-56.4% respectively; the contents of the cadmium and the lead of agricultural products are lowered by 13.6-43.9% and 22.1-53.2% respectively; and the soil pH value is also improved by 0.21-0.46%. The composite passivant has various functions of passivating soil heavy metal, repairing acidification soil and improving the soil tilth and the like.

Description

technical field [0001] The invention belongs to the technical field of agricultural environment conservation and restoration, and more specifically relates to a compound passivator for heavy metals in polluted soil, and also relates to a preparation method for a compound passivator for heavy metals in polluted soil, which is suitable for various heavy metals Contaminated soils, especially those with a heavy texture. Background technique [0002] With the continuous advancement of industrialization and urbanization, the problem of heavy metal pollution in my country's soil has been paid more and more attention by people. According to relevant reports, in the early 1980s, the area of ​​cultivated land polluted by heavy metals such as cadmium, lead, mercury, arsenic, chromium, and nickel in my country was only 2.67 million hm 2 , increased to 6.67 million hm in 1988 2 , had exceeded 10 million hm by the end of the last century 2 , has exceeded 20 million hm 2 , accounting f...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K17/06B09C1/08
Inventor 黄道友刘守龙朱奇宏罗尊长孙楠饶中秀雷敏曹晓玲朱昌宇周斌
Owner INST OF SUBTROPICAL AGRI CHINESE ACAD OF SCI
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