The invention relates to a
polyamide acid solution and a preparation method thereof, in particular to an environment-friendly stable
polyamide acid solution and a preparation method thereof. The environment-friendly stable
polyamide acid solution and the preparation method thereof aim at solving the problems of difficultly of large-scale preparation of a polyamide acid
aqueous solution, wide molecular
weight distribution and poor batch stability in the prior art. The environment-friendly stable polyamide acid solution is prepared from
tertiary amine, aromatic primary amine, aromatic dianhydride,
aromatic diamine and water, wherein repetitive units of polyamide acid in the polyamide acid
aqueous solution are shown in the specification. The preparation method includes the steps that
tertiary amine, aromatic primary amine, aromatic dianhydride,
aromatic diamine and water are taken, and weighed
tertiary amine is divided into
tertiary amine A and
tertiary amine B; water and aromatic primary amine are added into a three-necked
bottle under certain conditions for a reaction; weighed
tertiary amine A and weighed
aromatic diamine are added into the three-necked
bottle for a reaction, reaction liquid is heated, then weighed aromatic dianhydride is added into the three-necked
bottle and stirred for a reaction, then the reaction liquid is cooled, weighed tertiary amine B is added and stirred for a reaction, and the reaction liquid is cooled and subjected to standing.