The invention discloses a chemical industry wastewater purifying agent and a preparation method thereof. The purifying agent contains the following raw materials in parts by weight: 10-30 parts of aluminum oxide, 20-30 parts of decyl aldehyde, 20-25 parts of calcium oxide, 7-10 parts of sulfur, 36-40 parts of activated charcoal, 10-20 parts of polyacrylamide, 20-30 parts of cobalt oxide, 20-25 parts of sodium carboxymethyl cellulose, 25-30 parts of polyoxyethylene propylene glycol monostearate, 5-10 parts of camphor, 30-50 parts of sodium dodecyl sulfonate, 10-30 parts of hexamethylene tetramine and 20-39 parts of surfactant. The preparation method comprises the steps of uniformly mixing the raw materials, heating to the temperature of 40-60 DEG C, reacting for 1-2h, and then, cooling to room temperature, thereby obtaining the purifying agent. The purifying agent has a very good purification effect on chemical industry wastewater, suspended substances and ammonia nitrogen in the chemical industry wastewater can be purified effectively, the COD (Chemical Oxygen Demand) removal effect is relatively good, the pH value can be close to neutrality, and then, the pollution to water sources is prevented.