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179 results about "Mercapto compound" patented technology

The prefix mercapto- is placed before the name of a compound…. chemical compound: Thiols. A thiol is structurally similar to an alcohol but contains a sulfur atom in place of the oxygen atom normally found in an alcohol.

Stabilized infrared-sensitive polymerizable systems

The use of certain mercapto compounds as shelf life improvers for infrared-sensitive lithographic printing plate precursors is disclosed. The compounds are five-membered heteroaromatic rings containing a nitrogen atom and at least one other heteroatom, which can be oxygen, sulfur, or another nitrogen atom, such that two ring heteroatoms are bonded to a ring carbon bearing a thiol group.
Owner:KODAK POLYCHROME GRAPHICS

Sealing material for plastic liquid crystal display cells

An object of the invention is to provide a sealant composition for a plastic liquid crystal display cell that is capable of being applied to a sheet heat press adhesion method and of producing a plastic liquid crystal display cell having high reliability under a high temperature and high humidity environment. A two-component sealant composition for a plastic liquid crystal display cell of the invention contains the following components (1) to (6): (1) from 15 to 84% by weight of a liquid epoxy resin having from 1.7 to 6 in weight average of epoxy groups in one molecule and an ionic conductivity of an aqueous solution obtained by extraction separation by contact mixing with 10 times by weight of pure water at from 40 to 80° C. of 2 mS / m or less, (2A) from 10 to 50% by weight of a curing agent containing one or a mixture of two or more selected from (2A-1) a tetrafunctional mercapto compound or (2A-2) a modified polymercapto derivative, having an ionic conductivity of an aqueous solution obtained by extraction separation by contact mixing with 10 times by weight of pure water at from 40 to 80° C. of 0.6 mS / m or less, (3) from 0.01 to 15% by weight of a curing accelerator, (4) from 5 to 50% by weight of an inorganic filler, (5) from 0.1 to 5% by weight of a silane coupling agent, and (6) from 1 to 25% by weight of rubbery polymer fine particles having a softening temperature of 0° C. or less and an average particle diameter of primary particles of from 0.01 to 5 mum.
Owner:MITSUI CHEM INC

Preparation method of hyperbranched polymer-modified nano-silicon dioxide hybrid material

The invention relates to a preparation method of a hyperbranched polymer-modified nano-silicon dioxide hybrid material. The preparation method comprises the following steps: grafting a mercapto group-containing silane coupling agent to the surface of nano-silicon dioxide, utilizing a surface mercapto group and polyfunctional acrylic ester to perform click reaction to form the modified nano-silicon dioxide with the tail end of the acrylic ester, further performing the click reaction with a polyfunctional mercapto compound to form the modified silicon dioxide with the tail end of the mercapto group, repeating the operation between the polyfunctional acrylic ester and the polyfunctional mercapto compound for multiple times, and forming a hyperbranched polymer on the surface of the silicon dioxide. The hyperbranched polymer-modified nano-silicon dioxide hybrid material prepared by the preparation method provided by the invention has the mercapto group at the tail end and a hyperbranched structure, when the hyperbranched polymer-modified nano-silicon dioxide hybrid material is applied in an ultraviolet curing coating, the heat resistance, the hardness, the wear resistance and other mechanical properties of the coating can be improved, and the hyperbranched polymer-modified nano-silicon dioxide hybrid material can particularly solve the problems of dispersion and migration of the nano-silicon dioxide in the ultraviolet curing coating and the problem of oxygen polymerization inhibition of the ultraviolet curing coating.
Owner:TAIYUAN UNIV OF TECH

Organic silicon electronic-pouring sealant with high refractive index and high transparency, as well as preparation and application thereof

The invention belongs to the field of electronic polymer materials and discloses an organic silicon electronic-pouring sealant with high refractive index and high transparency, as well as a preparation method and an application thereof. The method comprises the following steps of: adding olefin-based silane and a silanol type compound into an organic solvent, adding a catalyst, and reacting at the temperature of 50-100 DEG C for 3-12h to get an olefin-based silane oligomer precursor; dripping an olefin-based silane coupling agent solution into a mercapto-compound solution, and reacting at the temperature of 50-100 DEG C for 8-48h to get a mercaptosilane oligomer precursor; mixing the two precursors to get the organic silicon electronic-pouring sealant, and the curing method comprises the following steps of heating to the temperature of 80-140 DEG C and curing for 3-8h, wherein the refractive index after curing is 1.53-1.59, and the light transmittance is 94-99%. According to the preparation method disclosed by the invention, phenyl and a sulfur element are introduced into the organic silicon electronic-pouring sealant, a thermocuring cross-linking technology is adopted, and mercapto-alkenyl click chemistry thermocuring can occur rapidly, so that the refractive index, the light transmittance and the mechanical properties after curing can be improved.
Owner:GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI

Novel (poly)oxyalkylene block silyl ester copolymer, antifouling coating composition, antifouling coating formed from antifouling coating composition, antifouling method using antifouling coating composition and hull or underwater structure covered with antifouling coating

A (poly)oxyalkylene block silyl ester copolymer comprising silyl ester copolymer block units (A) and block units (B), the silyl ester copolymer block units (A) comprising (a) component units derived from a polymerizable unsaturated carboxylic acid silyl ester, and (b) polymerizable unsaturated monomer units other than the component units (a), the block units (B) derived from a mercapto compound represented by the following formula (1) or (2), and further an antifouling paint comprising the (poly)oxyalkylene block silyl ester copolymer. wherein R1 represents a hydrocarbon group or ether-bond-containing hydrocarbon group having a valency of 1 or higher and having 1 to 30 carbon atoms; R2 represents a bivalent hydrocarbon group having 1 to 30 carbon atoms or a group of the formula -CH(R3)-wherein R3 represents a group of the formula R4-O-R5, R4 representing a bivalent hydrocarbon group having 1 to 30 carbon atoms, and R5 representing a monovalent hydrocarbon group having 1 to 30 carbon atoms; X represents: ; n is an integer of 1 to 5; m is an integer of 1 to 100; l is an integer of 1 to 5; k is an integer of 0 to 100; a is an integer of 0 or 1; j is an integer of 1 to 50; and i is the valency of R1. The present invention enables forming an antifouling coating film which exhibits less cracking tendency, excellent adherence so as to ensure less peeling tendency and desirably controlled hydrolysis rate so as to be excellent in antifouling performance (antifouling activity), antifouling properties, in particular, antifouling properties in highly fouling environment and long-term antifouling properties.
Owner:CHUGOKU MARINE PAINTS

Preparation method of water-soluble Zn-doped CdTe quantum dot CdxZn1-xTe

The invention discloses a preparation method of a water-soluble Zn-doped CdTe quantum dot CdxZn1-xTe. The preparation method comprises the following steps of: mixing a cadmium salt and a zinc salt or oxides of cadmium and zinc with a water-soluble mercapto-compound in a water phase; injecting prepared tellurium hydride to obtain a CdxZn1-xTe precursor solution; putting the solution into a hydro-thermal reaction kettle; and reacting to obtain a CdxZn1-xTe fluorescent quantum dot. The method is implemented in a water phase, is safe, easy and convenient for operation, is easy for mass productionand is environmentally friendly; the obtained product has high performance; even Zn doping molar percentage (i.e., the molar percentage of Zn to Cd in CdxZn1-xTe) surpasses 70 percent, the obtained quantum dot has high fluorescent quantum yield and high light stability and can be widely applied to photoelectric conversion, luminous and display materials, biological detection and targeting tracing; and the content and the toxicity of Cd are greatly lowered.
Owner:WUHAN UNIV

Resin composition for urethane optical lens having excellent thermal resistance and reactivity

The present invention relates to a resin composition for a plastic optical lens, and more specifically to a resin composition for a urethane optical lens having high thermal resistance and high reactivity. The resin composition for an optical lens of the present invention uses an optical resin prepolymer which is obtained from a preceding side reaction of a mercapto compound and a -SH / -NCO of isophorone diisocyanate or dicyclohexylmethanediisocyanate in appropriate mole ratios. The use of isophorone diisocyanate or dicyclohexylmethanediisocyanate results in enhancement of the thermal resistance of the optical lens, and the use of optical resin prepolymer at 20 to 70 weight % of the total weight of the resin composition for the optical lens, elutes the adhesive from adhesive tape due to lowered reactivity which results in a higher temperature reaction thereby resolving the problems of whitening phenomenon and foaming which occur on the edge of the lens due to a leak of the liquid composition when the reaction temperature increases.
Owner:KOC SOLUTION

Biological desulphurization process for waste and old rubber

The invention relates to a biocatalytic desulfurization method for waste rubber. The target desulfurization method adopts a plurality of hydrosulphonyl (-SH) compound in a microbial cell to catalyze and fracture the chain of the cross bond of perduren. The method comprises the following steps that: cyclane is added into a solution containing a phase change catalyst drop by drop under the heating and high-speed stirring conditions to prepare an emulsion, vulcanized rubber powder is added into the emulsion and is stirred to ensure that the rubber powder swells sufficiently, after the process, the microorganism containing a mercapto-compound is added to perform the desulfurization reaction, after the reaction is over, the mixture is pumped, filtered as well as washed and dried to obtain the vulcanized rubber powder. In the method, the desulfurization efficiency is high, the desulfurization process is simple, the production cost is low, and the microorganism is easily available without special breeding. The desulfurized rubber powder can be directly plasticated and pressed to form and can be added into the novel rubber to prepare rubber products together with the novel rubber.
Owner:BEIJING UNIV OF CHEM TECH

Method for preparing all-bio-based photocuring activated monomer and application of all-bio-based photocuring activated monomer

The invention discloses a method for preparing an all-bio-based photocuring activated monomer and an application of the all-bio-based photocuring activated monomer. The preparation method includes the steps that a bio-based hydroxyl compound containing stiffness rings or a modified bio-based hydroxyl compound containing stiffness rings, triethylamine and solvent are mixed, undecylenylacyl chloride is dripped slowly under the ice-bath condition, the temperature is rise to an indoor temperature to further react for 12-36 hours after reacting is conducted for 2-4 hours, suction filtration, liquid phase washing, drying, suction filtration and rotary evaporateion are carried out, and accordingly the all-bio-based photocuring activated monomer is obtained. According to the application of the all-bio-based photocuring activated monomer, 5-40 parts of all-bio-based photocuring activated monomer, 100 parts of all-vegetable-oil-based polyenoid photocuring prepolymer, 10-60 parts of multi-mercapto compound and 2-8 parts of UV-light 1173 photoinitiator, by weight, are evenly mixed, and then an all-bio-based ultraviolet curing coating is obtained. Double bonds contained in the all-bio-based photocuring activated monomer prepared through the method are located at the end positions, so that the reactivity is high. The content of renewable carbon atoms is 100%, and thus dependence on oil resources is relieved.
Owner:JIANGXI SCI & TECH NORMAL UNIV
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