The invention discloses a
flame-retardant
monomer containing DOPO (9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-
oxide) groups, and a preparation method and an application of the
flame-retardant
monomer, and relates to a compound. The method comprises the steps of sequentially adding an
organic solvent,
carbon tetrachloride and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-
oxide into a reaction flask, putting in an
ice water bath, adding hydroxyethyl methylacrylate and an acid-binding agent while stirring, after temperature rise reaction, decompressing, and performing suction
filtration to remove acid-binding agent salt, purifying a crude product through spin
steaming, washing and
dryness, and obtaining a product, namely the
flame-retardant
monomer containing the DOPO groups. The flame-retardant monomer containing the DOPO groups can be applied in preparing a flame-retardant high molecular material. A reaction condition is mild, the productivity is high, the product purification and separation are simple, and the extended production is easy. The monomer is introduced into a
polymer matrix such as
polystyrene and
polymethyl methacrylate by a free radical copolymerization manner, an intrinsic flame-retardant
polymer material is prepared, and the defects of poor compatibility of an additive flame retardant and the matrix, high loss possibility during use, poor
water resistance and the like are overcome.