This invention includes a kind of face baking-free formaldehyde coating dying nanometer adhesive water latex, the adhesive borns from the following steps. The pre-crosslinking monomer, soft monomer, hydrophilic monomer, anion and the non-ion types emulsify complex emulsifying agent and initiator. It is to get together the precrosslinking monomer, soft monomer, hard monomer, water hydrophile monomer , and get close to water get the hybrid body and initiator aqueous solution to join to emulsify to respond, moderate in the distilled waters, filter to make. This latex not only make in simple method, but also print to dye to process the application in the textile product, needing below 100 deg.C to dry but did not need to be baked, the hand feeling is soft, the degree of the wet or dry friction meets the request.