The invention relates to a production method of di(tert-butylperoxy)ketal, and mainly solves the problems of low product content, low yield, deep color and low production safety caused by violent
side reaction in the previous technique. In the invention, R1 selected from
cyclohexanone, 3,3,5-trimethylcyclohexanone or butyl levulinate and R2 tert-butyl hydroperoxide, which are used as raw materials, react in the presence of
solvent at -20-40 DEG C under normal pressure for 0.5-10 hours to obtain the corresponding product 1,1-di(tert-butylperoxy)
cyclohexane, 1,1-di(tert-butylperoxy)-3,3,5-trimethylcyclohexanone or 4,4,-di(tert-butylperoxy)-n-butyl
valerate, wherein the mol ratio of R2 to R1 is (2-10):1, the weight ratio of
solvent to R1 is (0.01-0.50):1, and the amount of the
solvent accounts for 20-80% of the total weight of the reactants R1 and R2; and the catalyst is selected from at least one of
sulfuric acid,
phosphoric acid,
hydrochloric acid,
perchloric acid, p-methylbenzenesulfonic acid,
nitric acid or
acetic acid. The technical scheme provided by the invention solves the problems in the previous technique, and can be used for industrial production of di(tert-butylperoxy)ketal.