The invention provides a rapid preparing method of a Zr-based electrochemical amorphous alloy. The method comprises the following steps that firstly, Mg3B2, or Ca3P2 and zirconocene dichloride are put into a zirconium dioxide ball mill tank, then, benzene is used as an anti-bonding agent or diluting agent, and argon is inflated for sealing the tank; secondly, positive rotation and reverse rotation crossing is carried out for ball milling; thirdly, in a vacuum glove box, the tank is opened, and in an ethyl alcohol solvent, after sediment is removed, a glass ware is sealed for standby application; fourthly, the ethyl alcohol serves as the solvent, polycation salt serve as a first main salt main component, third-period later-transition group element acetate including Cu serve as a second main salt main component, tetra-n-butylammonium bromide serves as conductive salt, alkali metal oxalate, citrate, tartrate or ethylene diamine tetraacetic acid serves as a complexing agent, and under a certain current density, a selected steel workpiece base body is plated.