The invention discloses an
indium sulfide photocatalyst with
sulfur vacancies. The
indium sulfide photocatalyst has a molecular formula of In2S3, abd is used for high-efficiency solar
nitrogen fixation. A preparation method of the catalyst comprises the following steps: 1, taking an organic liquid as a
solvent; 2, adding an organic substance and an
indium salt compound to the
organic solvent; 3, filling a reaction kettle with the obtained solution, and performing a constant temperature reaction; 4, cooling the obtained solution to
room temperature, centrifuging the cooled solution, respectively washing the obtained
reaction product with the
organic solvent and an
ethanol solution,
drying the washed
reaction product, and collecting the obtained
powder to obtain MIL-68(In); 5, adding an organic
sulfide to an organic
alcohol solvent, and performing mixing and sufficient stirring; 6, adding MIL-68 (In), and performing mixing and sufficient stirring; 7, filling the reaction kettle with theobtained mixture, and carrying out a constant temperature reaction; 8, cooling the obtained solution to
room temperature, centrifuging the cooled solution, washing the obtained
solid with water and the
ethanol solution respectively,
drying the washed
solid, and collecting the obtained
powder to obtain indium sulfide; and 9, annealing the indium sulfide in a
nitrogen atmosphere to produce
sulfur vacancies. The catalyst obtained by the method of the invention has the advantages of
environmental protection, harmlessness, realization of
batch production, and efficient solar
nitrogen fixation performance.