The invention discloses a composite carbon barrier coating for a polycrystalline silicon ingot furnace, which is used to coat the surface of a carbon material device in the ingot furnace to prevent carbon pollution, and is characterized in that: the composite carbon barrier coating includes coating A first coating composed of metal tungsten or metal molybdenum coated on the surface of the device, and a second coating coated on the first coating, the second coating is a silicon nitride layer or a silicon nitride layer In the laminated layer formed with the silicon oxide layer, the thickness of the first coating is 0.02-300 microns, and the thickness of the second coating is 0.02-300 microns. The invention also discloses a method for preparing the composite carbon barrier coating; at the same time, the invention also discloses a graphite guard plate and a polysilicon ingot furnace comprising the composite carbon barrier coating. The present invention eliminates the generation of carbon monoxide by coating the composite carbon barrier layer on the surface of the carbon material device in the polycrystalline ingot furnace, thereby reducing the impurities in the ingot polysilicon and the dislocations derived from the impurities, improving the crystal quality, and further Improve the conversion efficiency of solar cells.