The invention discloses a dicaryon
cadmium organic framework complex as well as a preparation method and application thereof. A
chemical formula of the complex is [Cd2(Mu3-cpima)(Mu3-Hcpimda)(H2O)]n,wherein H3cpimada is 1,4-benzoyl-2-propyl-1H-
imidazole-4,5-
dicarboxylic acid, H2cpiama is another ligand generated by the ligand H3cpimda in reaction through
decomposition, namely 1,4-benzoyl-2-propyl-1H-
imidazole-4-
formic acid. The preparation method comprises the following steps: adding 1,4-benzoyl-2-propyl-1H-
imidazole-4,5-
dicarboxylic acid and
cadmium chloride in the
molar ratio of 1:2 into H2O and
acetonitrile in the volume ratio of 10:2, and carrying out reaction for 72 hours at the temperature of 160 DEG C in a closed reaction kettle, so that colorless bulk crystals are obtained, and yield is 67%. The complex disclosed by the invention has a two-dimensional skeleton structure, and center
metal cadmium (II) ions respectively adopt a
hexa-coordinate mode and a seven-coordinate mode. When a light with the
wavelength of 340nm is used for exciting the
solid-state complex, the emission peak of the complex appears at 400nm, CIE
color coordinates are (0.24, 0.21) and are located in a
blue light region, and the complex can be applied as an optical material.