The invention relates to a preparation method of a quickly-rechargeable long-life high-voltage lithium cobaltate positive electrode material. The preparation method comprises the following steps: preparing Li<2>CO<3> and Co<3>O<4> as raw materials, adding a doping element M, adding a grain refiner and a cosolvent, and performing first sintering; and adding a grain refiner and a coating compound into a firstly-sintered material serving as a raw material, and performing surface coating and second sintering, wherein the doping element M is one or more of Ti<4+>, Zr<4+>, Mn<4+>, Sn<4+>, Ce<4+>, Ir<3+>, Mg<2+>, Al<3+>, V<5+>, Nb<3+> and Co<2+>, a molecular formula of doped lithium cobaltate is LiCo<1-x>M<y>O<2-y>; and the grain refiner is one or more of oxides of Ti, Nb, V, Al and Zr. The prepared lithium cobaltate positive electrode material has the characteristics of rapid charging, high capacity, high voltage, high cycle and low cost, can be applied under a rapid-charging high-voltage condition, and has superior electrochemical performance.