The invention discloses two magnetoelectric composite materials and a preparation method thereof. The magnetoelectric
composite material consists of a composite piezoelectric piece and a magnetostrictive
alloy Ni or magnetostrictive material Terfenol-D, wherein the composite piezoelectric piece is fixedly adhered to the magnetostrictive
alloy Ni or magnetostrictive material Terfenol-D through GE glue, and the composite piezoelectric piece is made by connecting a plurality of
layers of composite piezoelectric pieces in parallel; and the composite piezoelectric piece has great
capacitance, and the magnetoelectric
composite material has high magnetoelectric conversion sensitivity. The preparation method comprises the following steps of: firstly, adhering the composite piezoelectric piece and the magnetostrictive
alloy Ni or magnetostrictive material Terfenol-D through GE glue; secondly, baking and holding for 50 min at a temperature of 150 DEG C; and finally, naturally cooling to
room temperature to obtain the required magnetoelectric
composite material. The magnetoelectric composite materials have very high magnetoelectric sensitivity and inverse magnetoelectric effects at normal temperature, and the
sample preparation is simple, so that the materials can be
mass-produced; the compounding of the composite piezoelectric piece and the magnetostrictive alloy Ni requires a low bias ratio, so that the materials are favorable for application in practical devices; and the structure is simple, and the practicality is strong, so that the materials have stronger popularization and application values.