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319results about How to "High functionality" patented technology

Epoxy resin composition as well as prepreg and copper-foil-clad laminated board prepared by using same

The invention relates to an epoxy resin composition as well as a prepreg and a copper-foil-clad laminated board prepared by using the same. The epoxy resin composition comprises the following essential components: (A) epoxy resin containing a naphthol structure, (B) an active ester serving as a curing agent, and (C) a curing accelerant. Because epoxy resin at least contains the naphthol structure in the molecular structure, the epoxy resin composition provided by the invention has higher functionality degree and high glass transition temperature; at the same time, the naphthol group structure is introduced to the molecular structure, thus the cured product has low water absorptivity and low expansion coefficient; due to the active ester serving as the curing agent, the advantages that the a polar group is not generated during the reaction between the active ester and epoxy, thus the dielectric properties are excellent and moisture and heat resistance are good are fully exerted; and in addition, because of the epoxy resin containing the special naphthol structure, the hydroscopicity of the resin cured product is further reduced and the dielectric loss value of the cured product is lowered. The prepreg and the copper-foil-clad laminated board provided by the invention have excellent dielectric properties, moisture and heat resistance and high glass transition temperature.
Owner:GUANGDONG SHENGYI SCI TECH

Octa-epoxy cage type sesquialter siloxane and preparation thereof

The invention relates to octa-epoxy group cage-like silsesquioxane and a preparation method thereof. At present, the preparation of the cage-like silsesquioxane is generally not functionalized, and has a plurality of synthesis steps, low yield and too high cost. The cage-like silsesquioxane with epoxy groups is most noticeable with unique performance, but the existing cage-like silsesquioxane prepared by taking vinyl trichlorosilane as a raw material through hydrolytic condensation and oxidation is not completely epoxidized, and most of final products are mixtures. The preparation method takes industrialized tetramethyl orthosilicate or tetraethyl orthosilicate as a primary raw material, firstly synthesizes hydrated octa cage-like silicate through hydrolytic condensation, and then prepares the octa-epoxy group cage-like silsesquioxane with flexible chains through hydrosilation reaction and hydrosilylation reaction. The invention is simple and feasible, has high yield and single product structure, and is suitable for industrialized production; and the octa-epoxy group cage-like silsesquioxane has high reactivity, and is easily modified by being compounded with resins such as epoxy resin, phenolic resin, nylon, and the like so as to prepare composite materials with high performance.
Owner:BEIJING UNIV OF CHEM TECH

Biodegradation sustained-release fertilizer coating material containing soybean oil polyhydric alcohol and preparation process thereof

The invention relates to a biodegradation sustained-release fertilizer coating material containing soybean oil polyhydric alcohol and a preparation process thereof. The coating material is prepared by stirring a material A and a material B for 5s to 15s under the condition of 65 to 75 DEG C, wherein the material A accounts for 50 to 75 percent of the weight of the coating material, and the material B accounts for 25 to 50 percent of the weight of the coating material; the material A is one or combination of soybean oil polyhydric alcohol, polyether polyhydric alcohol and castor oil, and the material B is isocyanate. The soybean polyhydric alcohol prepared from the soybean oil which is low in price and easy to obtain is strong in water resistance, the coating material which is prepared from multiple functional groups and isocyanate is high in strength and biological degradability and environmentally friendly. By adopting the coating technology, no special equipment is needed, so that not only can the equipment investment cost be greatly reduced, but also the waste of solvent in the recycling process can be avoided, and the biodegradation sustained-release fertilizer coating material is free from polluting the soil, plants and the environment after being utilized for a long time.
Owner:MAOSHI AGRI TECH CO LTD

Plant-fiber-base polyether ester polylol, and preparation method and applications thereof

The invention discloses a preparation method of a plant-fiber-base polyether ester polylol, which belongs to the field of high polymer chemistry. The preparation method comprises the following steps:liquefying plant fiber materials and a liquefacient under the catalysis of an acid catalyst to obtain a liquefying product; and carrying out the reaction of the liquefying product and cyclic carboxylic ethers, open-chain hydroxyl carboxylic ethers or estolides, and the like under the catalysis of acids, organic tin compounds or titanic acid esters so as to obtain the polyether ester polylol. The method realizes the high functionality and the high reactive activity of the plant-fiber-base polyether ester polylol. The hydroxyl value and the relative molecular mass of the product can be regulatedby changing the material proportions and the technique conditions to obtain the required product so as to prepare the polylol material required by different polyurethane materials and enhance the performance of the polyurethane materials.
Owner:SOUTH CHINA UNIV OF TECH

Apparatus and method to test high speed devices with a low speed tester

An apparatus coupled to a low speed tester and a device is disclosed. The device may have a first speed faster than a second speed of the low speed tester. The apparatus may be configured to allow the low speed tester to perform high speed tests of the device at the first speed.
Owner:MONTEREY RES LLC

Biomolecular processing platform and uses thereof

The present invention relates to a device comprising a biomolecular processor. Each biomolecular processor has one or more bioreactor chambers defined by a solid substrate; a support structure within each bioreactor; a cleaving enzyme immobilized to the support structure and operatively positioned within the bioreactor chamber to cleave monomer or multimer units of a biopolymer molecule operatively engaged by the cleaving enzyme; and one or more time-of-flight channels formed in the solid substrate and fluidically coupled to said one or more bioreactor chambers. Each of the time-of-flight channels have two or more sensors including at least (i) a first sensor contacting the time-of-flight channel proximate to the input end of the channel and (ii) a second sensor contacting the time-of-flight channel proximate to the output end of channel. The present invention further relates to methods of sequencing and identifying biopolymer molecules using the device.
Owner:CORNELL UNIVERSITY +3

Epoxy resin composition, and prepreg and copper foil-clad laminated sheet prepared by using epoxy resin composition

The present invention relates to an epoxy resin composition, and a prepreg and a copper foil-clad laminated sheet prepared by using the epoxy resin composition. The epoxy resin composition comprises the following components: (A) an epoxy resin containing two or more than two epoxy groups, (B) an active ester curing agent, and (C) a phosphate compound. According to the epoxy resin composition of the present invention, the epoxy resin having a specific molecular structure is adopted, and functionality is high, such that the resulting cured product has characteristics of high glass transition temperature and low moisture absorption; the active ester is adopted as a curing agent, such that the advantage of the active ester is completely provided, wherein the advantage comprises that no polar group is produced when the active ester reacts with the epoxy resin so as to provide excellent dielectric property and good moisture heat resistance; with application of the active ester as the curing agent, water absorption of the phosphorous-containing component can be further improved, a water absorption rate and a dielectric loss value of the cured resin material can be reduced, and purposes of no halogen, fire retardation and good moisture heat resistance can be concurrently achieved; and the prepreg and the copper foil-clad laminated sheet in the present invention have characteristics of no halogen, fire retardation, excellent dielectric property and excellent moisture heat resistance.
Owner:GUANGDONG SHENGYI SCI TECH

Hyperbranched water-based polyurethane coating and preparation method thereof

The invention provides a hyperbranched water-based polyurethane coating and a preparation method thereof, belongs to the field of water-based coating, and is used for solving the problem that the existing hyperbranched water-based polyurethane is poor in waterproofness, solvent resistance and weather fastness. The coating comprises 35-68 parts of hyperbranched water-based polyurethane, 0.3-0.9 part of water-based wetting agent, 0.2-0.7 part of water-based flatting agent, 0.5-1.1 parts of water-based deformaer, 8-12 parts of water-based cosolvent and 2.5-4.3 parts of curing agent. The hyperbranched water-based polyurethane is prepared with hyperbranched polyester BoltornTMH40 as a soft segment and diaminosulfonate as a hydrophilic chain extender. A film formed by the cured hyperbranched water-based polyurethane coating provided by the invention has no phenomena of blushing, bubbling and falling even after being soaked in normal-temperature water for 60 hours, and also has no phenomena of blushing, facing and dulling even after being wiped 200 times by using ethanol and acetone.
Owner:CHANGCHUN SANHUA IND

Cashew nut shell oil-modified phenolic resin and preparation method for cashew nut shell oil polyether polyol prepared from same

The invention discloses cashew nut shell oil-modified phenolic resin and a preparation method for cashew nut shell oil polyether polyol prepared from the cashew nut shell oil-modified phenolic resin. The method for preparing the cashew nut shell oil-modified phenolic resin comprises the following steps: adding cashew nut shell oil and an acidic catalyst in a reactor; then adding a coupling agent by stirring to enable the coupling agent to be completely dissolved; and raising the temperature, reacting and dehydrating to obtain a product. The method for preparing the cashew nut shell oil polyether polyol comprises the following steps: adding a basic catalyst and an epoxy compound into the product; and rising the temperature, reacting, cooling and filtering to obtain the cashew nut shell oil polyether polyol. The polyether polyol prepared by the preparation method disclosed by the invention has the advantages of low viscosity, moderate functionality degree, no toxicity, regeneration and the like. The phenolic resin disclosed by the invention is used as intermediate resin. The cashew nut shell oil polyether polyol disclosed by the invention is applied to polyurethane coating and is used as hydroxyl-containing resin to be matched with an isocyanatec component to form a polyurethane coating system. The cashew nut shell oil polyether polyol has the characteristics of favorable corrosion resistance, in particular to alkali resistance, excellent mechanical performance and the like.
Owner:CARDOLITE CHEM ZHUHAI

Water dispersible hyperbranched polyisocyanate and preparation method thereof

The invention discloses water dispersible hyperbranched polyisocyanate and a preparation method thereof. The preparation method comprises that hyperbranched polyester with different generation quantities is synthesized while polyalcohol is taken as a core molecule, dimethylolpropionic acid is taken as a monomer and dimethylbenzene is taken as a solvent, end group modification is carried out on the hyperbranched polyester, a high reactivity isocyanate group is introduced for synthesizing hyperbranched polyisocyanate, and then waterborne treatment is carried out on the hyperbranched polyisocyanate, so that the water dispersible hyperbranched polyisocyanate is obtained. The preparation method is low in production cost and simple in technological equipment, and the prepared water dispersible hyperbranched polyisocyanate has high functionality degree, high reactivity and low viscosity, can be dispersed in water and can be used for improving the physical and chemical properties of a coating when being applied to a waterborne alkyd paint, a waterborne polyurethane coating and a waterborne acrylic coating as a curing agent.
Owner:武汉仕全兴聚氨酯科技有限公司 +1

Cross-linking waterborne polyurethane and preparation method thereof

The invention discloses a preparation method for cross-linking waterborne polyurethane. The preparation method comprises the following steps that 1, polyester polyol and diisocyanate are mixed, then acatalyst of dibutyltin dilaurate is dropwise added, nitrogen is introduced, and reaction is carried out; 2, a hydrophilic chain extender is added for reaction, then a end-capping chain extender is added for reaction, and after a neutralizer is added for reaction, water is added for dispersing so as to obtain a waterborne polyurethane emulsion; and 3, a multi-double-bond castor oil solution is added into the waterborne polyurethane emulsion, an initiator is dropwise added, reaction is carried out, and after the reaction is finished, a solvent is removed so as to obtain the cross-linking waterborne polyurethane. According to the method, the waterborne polyurethane emulsion is firstly synthesized, then free radical copolymerization reaction is carried out on multi-double-bond castor oil andthe waterborne polyurethane, the multi-double-bond castor oil is connected into a waterborne polyurethane structure so as to form the cross-linking waterborne polyurethane with a spatial network structure, and therefore the mechanical performance of the cross-linking waterborne polyurethane is improved; and the spatial density inside a polymer is increased, so that the space is shrunk, water molecules are difficult to enter, and therefore the water resistance is improved.
Owner:SHAANXI UNIV OF SCI & TECH

Polyisocyanates containing diphenyl-methane-group diisocyanate, and preparation method

The invention provides polyisocyanates containing diphenyl-methane-group diisocyanate, and a preparation method. The polyisocyanate has a structure ad follows. The preparation method comprises: taking diphenyl-methane-group diisocyanate monomers and trimer products thereof as main isocyanate raw materials; allowing the main isocyanate raw materials to react with functional organic silicon compounds; and obtaining a series of polyisocyanates. The polyisocyanates can be used as paint, ink and curing agents of adhesive, and have low viscosity, quick-drying property, high hardness, good adhesive force and other excellent performances.
Owner:武汉壁千韧硅涂料有限公司

Modified solid epoxy resin with high glass transition temperature and high tenacity as well as preparation method thereof

The invention relates to modified solid epoxy resin with high glass transition temperature and high tenacity. The modified solid epoxy resin is prepared from the following components in parts by weight: 100 parts of epoxy resin, 50-120 parts of a modifier, 0.05-5 parts of a catalyst, and 25-100 parts of a curing agent. The invention further provides a preparation method of the modified solid epoxy resin with high glass transition temperature and high tenacity. The modified solid epoxy resin has the excellent properties that the glass transition temperature is 128-178 DEG C, the cathodic cathodic disbonding radius is smaller than or equal to 10 mm (1.5 V, 92-98 DEG C, 28d), the modified solid epoxy resin can pass a bend test of 3 degrees at minus 30 DEG C as no crack generates, the softening point is 96-115 DEG C, the epoxide number is 0.19-0.275 mol / 100g, and the functionality degree is 2.6, so that the modified solid epoxy resin can be applied to the fields of petroleum and gas long-distance pipelines, urbane groundwater, gas pipe network pipelines, transportation industry (automobiles and ships), oceanographic engineering, corrosion prevention in bridges and construction reinforcing steel bar, and the like in which the use temperature is higher than 95 DEG C.
Owner:大庆庆鲁朗润科技有限公司

High-temperature-resistant polyether polyol and preparation method thereof

The invention belongs to the field of chemical synthesis, and particularly relates to high-temperature-resistant polyether polyol and a preparation method thereof. The high-temperature-resistant polyether polyol is characterized by being prepared from the following components in parts by weight: 600-1,000 parts of sorbierite, 300-600 parts of cane sugar, 3,300-3,800 parts of epoxy propane, 10-18 parts of potassium hydroxide, 20-36 parts of phosphoric acid and 140-200 parts of water. The method has the advantages: the prepared high-temperature-resistant polyether polyol is catalyzed by using potassium hydroxide; sorbierite is an ideal starting agent for preparing temperature-resistant polyether; and the polyether polyol synthesized by adopting sorbierite and cane sugar with high functionality has high functionality and low hydroxyl value. Hard urethane foam plastic prepared from polyether polyol has high heat resistance, high size stability, thermal oxidation resistance, oil resistance, bonding property and high size stability.
Owner:ZIBO DEXIN LIANBANG CHEM IND
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