The invention discloses a preparation method for cross-linking waterborne
polyurethane. The preparation method comprises the following steps that 1,
polyester polyol and diisocyanate are mixed, then acatalyst of
dibutyltin dilaurate is dropwise added,
nitrogen is introduced, and reaction is carried out; 2, a hydrophilic chain
extender is added for reaction, then a end-capping chain
extender is added for reaction, and after a neutralizer is added for reaction, water is added for dispersing so as to obtain a waterborne
polyurethane emulsion; and 3, a multi-double-bond
castor oil solution is added into the waterborne
polyurethane emulsion, an initiator is dropwise added, reaction is carried out, and after the reaction is finished, a
solvent is removed so as to obtain the cross-linking waterborne polyurethane. According to the method, the waterborne polyurethane
emulsion is firstly synthesized, then free radical copolymerization reaction is carried out on multi-double-bond
castor oil andthe waterborne polyurethane, the multi-double-bond
castor oil is connected into a waterborne polyurethane structure so as to form the cross-linking waterborne polyurethane with a
spatial network structure, and therefore the mechanical performance of the cross-linking waterborne polyurethane is improved; and the
spatial density inside a
polymer is increased, so that the space is shrunk, water molecules are difficult to enter, and therefore the
water resistance is improved.