The invention discloses solder used for the vacuum active brazing process of a W-Cu composite material and stainless steel and a preparation method. The selected solder comprises, by weight, 25%-33% of Cu, 1.0%-3.5% of Ti, 3.0%-5.0% of Ni, 1.0%-2.2% of Zr, 3.5%-7.0% of Mn and the balance Ag. The solder has good lubricity for the W-Cu composite material and the stainless steel, the melting temperature is low, and melting of the solder is uniform. The vacuum active brazing process by using the solder to connect the W-Cu composite material with the stainless steel is stable and reliable. Under the vacuum condition, a component is in a vacuum state in the heating process, and the whole component is free of deformation, microscopic cracks, pores, mixed impurities and other defects; by means of the high diffusibility and interface reaction ability of the active elements (the Ag, the Cu, the Ti, the Ni and the Zr), distribution of the active elements is uniform, crystal grains are fine, and residual stress is small; the overall strength of the connector is high, and the plastic deformation ability is high; operation is easy, convenient and efficient, and repeated representation can be achieved.