The invention discloses a high-phosphorous chemical nickel-plating solution which comprises a cylinder opening solution and a supplement solution. The cylinder opening solution contains nickel sulfate, sodium hypophosphite, citric acid, lactic acid, sodium acetate, succinic acid, potassium iodate, potassium iodide, nitrilotriacetic acid, cerous sulfate, copper sulfate, benzotriazole, benzimidazole with the concentration being 2-10 mg / L, 5-25 mL / L of OP-10 with the concentration being 5-25 mL / L and the balance pure water. The nickel-plating solution has the advantages that cost is low, the excellent plating ability is achieved, the cylinder opening solution is stable, glossiness is achieved, the magnetism level requirement is met, and the service life reaches 11.0 MTO; during the service life, the average sedimentation rate is 12-14 [mu]m / h, the phosphorus content of a plating layer is 10%-14%, the time for neutral salt spraying is longer than or equal to 96 h (the thickness of the plating layer is 18-25 [mu]m), and the time for a purification resistant nitric-acid test is longer than or equal to 8 min (the thickness of the plating layer is 18-25 [mu]m); the magnetism level is lower than or equals to 200 gamma (specifically, 1 gamma is equal to 1 nT, and in general, remanence in the aerospace field takes gamma as a unit), the western country standard is met, and the magnetism is required to meet the NMB magnetism level; and the plating solution is free of lead and cadmium, conforms to the RoHS command and is an environment-friendly high-phosphorous chemical nickel-plating solution.