The invention discloses a technology for treating a high-
arsenic copper material. The technology comprises the steps that the high-
arsenic copper material is subjected to crushing,
grinding,
sodium hydroxide mixing and oxidizing leaching,
copper in the high-
arsenic copper material is oxidized and left in residues in a residual mode along with lead and
noble metal of gold, silver and
platinum, arsenic enters a solution in a
sodium arsenate mode,
leachate is subjected to concentration and
crystallization, a
sodium arsenate product is obtained, and a concentrated solution returns to be subject to
oxygen-pressure alkali leaching; leached residues are subjected to sulfuric-acid
atmospheric pressure leaching, copper enters the solution in a
copper sulfate mode, acid adjustment is conducted, and vortex
electrolysis is directly conducted for extracting copper; electrodeposited waste liquid is recycled; and lead and the
noble metal enter lead and silver residues, and valuable elements of Pb, Ag and Au are comprehensively recycled. The technology belongs to a clean
metallurgy process, is low in equipment
corrosion-resistant requirement, free of
pollution to environment, easy to operate and high in comprehensive recycling degree of
metal and has the advantages of being higher in practicability and adaptability to raw materials and the like.