The invention discloses a preparation method of a mulberry
twig-based
solid acid. The preparation method comprises the steps: firstly washing cleanly impurities and mud on mulberry twigs, peeling,
drying, smashing, and thus obtaining a mulberry
twig powder; then mixing the obtained mulberry
twig powder with N-methyl
morpholine oxide according to a ratio of 1:8-10, stirring at the temperature of 80-100 DEG C with the stirring time of 0.5-3 h, and assisting with ultrasonic treatment to make fibers swelled, then washing to remove N-methyl
morpholine oxide, adding an auxiliary agent according to a ratio of the mulberry twig
powder to the auxiliary agent of 20:1 to make the mulberry twig powder activated, and
drying to remove water; then putting the obtained product into a
crucible, placing in a
tube furnace, adjusting the
furnace temperature to 400-500 DEG C, and carrying out heating treatment with
nitrogen protection and the
treatment time of 1-5 h; and finally, adding fuming
sulfuric acid according to a ratio of the mulberry twig powder to a 20% fuming
sulfuric acid of 1:1-5, treating, washing to remove impurities, and
drying to obtain the mulberry twig-based
solid acid. The
solid acid has the advantages of
small particles, good adsorption property on reaction substrates, good
catalytic effect, high
thermal stability, high
acid value, and low cost, and the raw materials are waste materials.