A new harmless comprehensive utilization technique for wet
processing chromic
slag comprises steps as follows: ball milling chromic
slag to 80-200 meshes, adding water to prepare
slurry, immersing the
slurry in
hydrochloric acid solution, regulating the pH to 5-6, performing
solid-liquid separation with
filter press, in the immersion liquid after separation, the hexavalent chrome is reduced to trivalent
chromium, adding
sodium hudroxide
aqueous solution, regulating the pH to 4-6, roughly preparing chromic
hydroxide, adding
sulfuric acid into filtrate, regulating the pH to 5-6, removing the
calcium coprecipitated with
magnesium in the rest filtrate, preparing the 2-water
calcium sulphate
whisker, adding alkali to the filtrate after filter-pressing to regulate the pH to 9-12 to synthesize super-fine
magnesium hydroxide powder; the solution after filter-pressing is concentrated to prepare
sodium chloride. The main contents of extracts within the chromic
slag treated by wet
processing all can meet primary, secondary or even accredited national or ministerial standard. The technique can thoroughly detoxicate Cr<6+> in chromic slag and can prepare nine products, includiing chromic
hydroxide,
magnesium hydroxide,
ammonium hydroxide,
silicon dioxide, magnetic
ferrous ferricoxide, 2-water
calcium sulphate,
corundum intermediate,
sodium chloride, and
tailings-
chromite; and the extracts after
processing chromic slag have high quality.