The invention relates to an adsorption material for treating phosphorus wastewater and use thereof. The adsorption material consists, by mass percent, of 50 to 70% of flyash zeolite and 30% to 50% of natural zeolite and is prepared by homogenously mixing the flyash zeolite with the natural zeolite based on the above proportion, the above resultant adsorption material is added, with the mass ratio of phosphorus to the adsorption material being 1: 100 to 200, to phosphorus wastewater with the pH from 3 to 10 and the phosphorus concentration from 0 to 150mg / l in order to treat the phosphorus wastewater, the contact time is 1 hour, the removal rate of phosphorus is larger than 90%, and the pH of zeolite subsequent to treatment is close to be neutral. The flyash zeolite resulting from modified synthesis in the invention not only has significant phosphorus adsorption effect, but can also realize the effective utilization of wastes to reduce the pollution of flyash to environment. Mutual combination of the flyash zeolite and the natural zeolite results in synergistic action for phosphorus adsorption, reducing the content of phosphorus in wastewater effectually. Therefore, the adsorption material of the invention for treating phosphorus wastewater has the advantages that the adsorption capacity is high, the utilization of wastes is favorable for environmental protection and the like.