The invention provides a desulphurization catalyst which can substantially improve desulphurization efficiency, reduce
system obstruction and
fouling, prevent foaming and overflow of a
slurry pump and reduce
energy consumption of
system, and a limestone-
gypsum wet desulphurization technology used for large-scale thermal power, belonging to the technical field of environment protection. The catalyst comprises components by weight percent: 40-70 % of organic polyprotic acid or
sodium salt thereof, 0.1-5 % of
transition metal salts, 5-15 % of a
pH buffering agent, 0.05-2 % of a surfactant and 5-20 % of a scale inhibitor. The catalyst is characterized in that a synergist can be directly added into a filtrate pit of an absorbing
tower, uniformly stirred and dissolved and then pumped into the absorbing
tower; or the synergist can be mixed with a limestone
powder into a certain concentration and then added. By using the
flue gas desulphurization catalyst, buffer capacity of a pH value of the
slurry is relatively good, an
oxidation rate of
sulfite is accelerated by more than 30 %, a desulphurization efficiency is improved by 10 %, residual CaCO3 in the
gypsum is reduced to be less than 1 %, a
water content is reduced to be more than 2 %, distribution of
crystal size is relatively uniform, share of rhombic
crystal shapes and columnar shapes are increased, a specific surface area of the
crystal is increased and a dehydrated performance of the
gypsum is relatively good.