The invention relates to a nido-
carborane containing organometallic compound
crystal and a preparing method thereof, and belongs to the technical field of
organometallic chemistry. The structure of the compound is represented and determined by monocrystalline X-
ray diffraction,
nuclear magnetic resonance, and other methods. The
crystal belongs to the monoclinic
system and a
space group P2<1> / n. The molecular formula of the
crystal is C<27>H<37>B9ORuS2, and the molecular weight is 640.05. According to
cell parameters, a is equal to 17.8494(15) angstroms, b is equal to 10.2272(9) angstroms, c is equal to 18.7853(16) angstroms, alpha is equal to 90 degrees, beta is equal to 92.9220 (10) degrees and gamma is equal to 90 degrees. 1,2-dicarba-closo-dodecaborane, n-
butyllithium,
sulfur powder, dichloro(p-cymene)
ruthenium(II)
dimer and 1,1-diphenyl-2-propyn-1-ol are adopted as raw materials and prepared under mild conditions into the nido-
carborane containing organometallic compound that is (p-cymene)Ru(S2C2B9H<10>)(CH-C=C(Ph)<2>).H2O, wherein the p-cymene is 1-methyl-4-
isopropyl phenyl. The compound has characteristics of the simple preparing method, a high yield, good
repeatability, and the like and provides a novel idea for development of
carborane-containing novel materials having good performance and application prospects.