The invention discloses a preparation method of a ZrO2
nanotube supported B2O3 catalyst, which comprises the following steps of: preparing
aqueous solution containing NH4F with the concentration of 0.5 to 1.0%,
boride with the concentration of 0.1 to 6% and (NH4)2SO4 with the concentration of 5 to 12%, taking the
aqueous solution as reaction medium, taking a
zirconium plate as
anode and a
platinum plate as
cathode with the spacing of 1.5cm therebetween, adopting 10-30V
direct current for
anode oxidation for 3 to 5 hours at
room temperature, stopping reaction,
drying and
roasting the
resultant oxide to obtain the catalyst, wherein all the concentration percents are
mass percents. The B2O3 / ZrO2 catalyst prepared according to the method of the invention has large specific surface area and volume simultaneously, and when the specific surface area thereof is the same as that of nano
powder, the volume is ten thousand times as much as that of nano
powder, thus the contradiction between specific surface area and volume of
powder carrier is settled, and the defects caused by the fact that powder ZrO2 supports the B2O3 catalyst can be overcome.