The invention relates to a chemical industrial product, and especially relates to a paint containing photo-induced energy-storage luminous powder. The paint containing the photo-induced energy-storage luminous powder comprises the following components by weight ratio: 5-5.5% of barium sulfide, 3-4% of magnesium sulfide, 1.5-2.2% of aluminum sulfide, 2-3% of potassium nitrate, 20-30% of tung oil, 10-16% of epoxy resin, 5-11% of acrylonitrile, 3-6% of modified alkyd resin, 5-8% of methacrylic resin, 0.5-1% of turpentine, 1-3% of a propylene pigment, 3-6% of a photoinitiator, 5-10% of polyvinyl butyral, 3-5% of an antifoaming agent and the balance of a thinner. The paint containing the photo-induced energy-storage luminous powder has the advantages of strong covering power, good gloss retention, color retention and weatherability, and fast drying speed; can absorb yellow light emitted under dark environment, and can be used for objects such as guideboards, outdoor advertisements, night roads and obstacle marks.