According to a process for preparing high-purity artificial fluorite by recovering fluoride-containing wastewater, a fluidized bed serves as a crystallization treatment device, fluoride components in wastewater are efficiently extracted in a supporter crystallization mode, a high-purity calcium fluoride artificial fluorite product is prepared, fluoride-containing wastewater can be treated to reach the standard, no secondary pollution exists, the problems of land occupation and environment pollution of bottom mud produced during treatment of industrial fluoride-containing wastewater are solved, fluoride resources in the bottom mud are effectively used, circulation is short, operation is simple, implementation is easy, fluoride pollution and fluoride resource waste are reduced, and process efficiency is high; good balance can be achieved between making emission not exceed the standard and controlling wastewater treatment cost. Produced calcium fluoride crystals are suitable for preparing artificial fluorite to serve as the substitute of natural fluorite, calcium fluoride crystals produced in the technological process are low in water content, fluoride-containing waste reducing or resourceful using aim is effectively achieved, and the process is an environment-friendly method for treating high-concentration fluoride-containing wastewater and is wide in industrial application prospects.