The invention provides a method of one-pot
cascade catalytic copolymerization of
ethylene and 1,2-disubstituted polar isomerised olefin
monomer represented as the formula (I) and a product of the method. The method includes: performing an
ethylene decomposition reaction on a 1,2-disubstituted polar isomerised olefin
monomer and an
ethylene monomer in the presence of a
ruthenium catalyst Ru-1 or Ru-2 at 20-50 DEG C to form an ethylene
decomposition monomer product; then performing a copolymerization reaction on the ethylene
decomposition monomer product and the ethylene monomer in the presenceof a
palladium phosphinosulfonate catalyst PO-Pd or PO-Pd* at 70-90 DEG C, wherein the R1 and R2 in the formula (I) are defined as the specification. By means of the specific Ru and Pa catalysts, a novel process of the
cascade copolymerization of the 1,2-disubstituted polar isomerised olefin monomer, capable of being derived from
biomass, and the ethylene monomer under a gentle condition, thus obtaining the functionalized polar
copolymer having a specific performance. In addition, the invention fills the technical gap of the copolymerization of the 1,2-disubstituted polar isomerised olefin, capable of being derived from
biomass, and the ethylene monomer to produce the functionalized polar
copolymer.