The invention discloses a crosslinked polyvinyl chloride material and a preparation method thereof. The crosslinked PVC material is prepared from the following raw materials in parts by weight: 100 parts of PVC, 1-3 parts of a crosslinking agent, 5-20 parts of an acid acceptor, 2-5 parts of a stabilizer, 5-45 parts of a plasticizer and 0.2-1.5 parts of a lubricant. The preparation method comprisesthe following steps: putting the materials into a high-speed stirrer, stirring at a high speed for 10-15 minutes to uniformly mix all materials, carrying out melt blending on the mixture in a double-roller plastic mixing mill, discharging sheets, carrying out vulcanization molding in a press vulcanizer, transferring into a plate cold press, shaping, and finally cutting as required. By using the novel cross-linking agent, the cross-linking rate can be increased, the cross-linking degree can be improved, high cross-linking density can be achieved in a short time, time can be saved, and the efficiency can be improved. The obtained material is excellent in mechanical property, the heat resistance is obviously improved, and the use requirements of various materials can be met at a high temperature.