The invention relates to a
temperature sensitive polyvinylidene fluoride (PVDF) gel film and a preparation method thereof. The
temperature sensitive PVDF gel film comprises the following components in percentage by weight: 0.5-2.5 percent of
temperature sensitive high polymer gel and 97.5-99.5 percent of PVDF
polymer. The preparation method comprises the steps of: a, preparing the temperature sensitive
high polymer gel: dissolving a
temperature sensitive polymer monomer and a crosslinking agent into absolute ethyl
alcohol, carrying out
radical polymerization under the protection of
nitrogen to obtain the temperature sensitive
high polymer gel; b, preparing a film
casting solution, dispersing the temperature sensitive high
polymer gel obtained from the step a in an
organic solvent, gradually adding a certain quantity of PVDF
powder, dissolving, degassing to obtain the film
casting solution; and c, preparing the gel film: scraping the film
casting solution obtained from the step b on a clean and
flat glass plate to form a liquid film, curing in a curing bath to form the film. The PVDF gel film prepared by using the method has aperture size
ranging from 100 to 300nm, the surface in ahole of the PVDF gel film consists of the temperature sensitive high
polymer gel, the temperature sensitive high
polymer gel can generate response according to the environment temperature change so as to cause that the film
hole size is changed; and the invention can be used in intelligent selective separation of separated matters.