The invention discloses an organic light-emitting
superlattice film and a preparation method and application thereof, and belongs to the field of
organic semiconductor photoelectric materials. The organic light-emitting
superlattice film is an organic light-emitting film formed by alternate epitaxial growth of two two-dimensional
organic molecules on the surface of a substrate, and the two-dimensional
organic molecules are selected from 3,4,9,10-
perylenetetracarboxylic dianhydride, N,N'-dimethyl-3,4,9,10-
perylenetetracarboxylic diimide, N,N'-dioctyl-3,4,9,10-perylenedicarboximide and 3,4,9,10-
Perylenetetracarboxylic diimide. The preparation method comprises the following steps: placing a growth
source material of a first two-dimensional organic molecule and a substrate at different positions of a
tube furnace, and epitaxially growing a first layer of organic light-emitting film on the surface of the substrate; replacing a growth
source material with a second two-dimensional organic molecule, and growing a second layer of organic light-emitting film; and repeatedly replacing the growth
source material, and alternately growing multiple
layers of organic light-emitting films to obtainthe organic light-emitting
superlattice film. The organic light-emitting superlattice thin film has high quality and high light-emitting intensity, and can be used as a light-emitting layer of an organic light-emitting
field effect transistor.