The invention discloses a self-cleaning, flame-retardant and corrosion-resistant fluorosilicon powder coating, which comprises the following components in parts by weight: 50-60 parts of film-forming copolymer, 4-8 parts of quaternary ammonium salt of amino-terminated hyperbranched compound , 1-3 parts of lignosulfonic acid, 0.1-0.2 parts of phosphorus pentoxide, 3-7 parts of functional additives, 10-15 parts of inorganic fillers, 1-3 parts of rare earth fluoride nanofibers; the film-forming copolymer is 2-trimethylsiloxy-1,1,1,5,5,5-hexafluoro-2-pentene-4-one, (E)-4-(2-cyano-3-ethoxy 3-oxo-1-propenyl) pinacol phenylboronate, trimethyl 4-phosphocrotonate, N-hydroxysuccinimidyl methacrylate, 1,3-bis(oxirane (methyl)-5-(2-propenyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione by free-radical copolymerization. The powder coating disclosed by the invention has remarkable self-cleaning effect, good performance stability, corrosion resistance, weather resistance, wear resistance, film forming property, and flame retardancy, good bonding performance with the base material, excellent comprehensive performance, and safe use Environmental friendly.