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Self-cleaning flame-retardant corrosion-resistant fluorosilicone powder coating

A powder coating and corrosion-resistant technology, applied in the field of coatings, can solve the problems of complex raw materials of coatings, the stability of coating properties needs to be further improved, and high preparation costs, and achieve high production efficiency and yield rate, remarkable self-cleaning effect, flame retardancy Good results

Active Publication Date: 2020-11-13
东莞市正荣实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this kind of weather-resistant self-cleaning coating has complex raw materials, high preparation costs, and the performance stability of the coating needs to be further improved.

Method used

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  • Self-cleaning flame-retardant corrosion-resistant fluorosilicone powder coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A self-cleaning flame-retardant and corrosion-resistant fluorosilicone powder coating is characterized in that it comprises the following components by weight: 50 parts of film-forming copolymer, 4 parts of amino-terminated hyperbranched compound quaternary ammonium salt, lignin sulfonate 1 part of acid, 0.1 part of phosphorus pentoxide, 3 parts of functional additives, 10 parts of inorganic fillers, 1 part of rare earth fluoride nanofibers; the film-forming copolymer is 2-trimethylsiloxy-1,1, 1,5,5,5-hexafluoro-2-penten-4-one, (E)-4-(2-cyano-3-ethoxy-3-oxo-1-propene)phenylboronic acid Nacolate, trimethyl 4-phosphocrotonate, N-hydroxysuccinimidyl methacrylate, 1,3-bis(oxiranylmethyl)-5-(2-propenyl)- 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione is prepared by free radical copolymerization.

[0027] The inorganic filler is attapulgite; the functional auxiliary agent includes a defoamer, a dispersant, and a wetting agent; the mass ratio of the defoamer, a dispersant, and a wetti...

Embodiment 2

[0032] A self-cleaning flame-retardant and corrosion-resistant fluorosilicone powder coating is characterized in that it is made of the following components in parts by weight: 53 parts of film-forming copolymers, 5 parts of amino-terminated hyperbranched compound quaternary ammonium salts, lignin sulfonate 1.5 parts of acid, 0.12 parts of phosphorus pentoxide, 4 parts of functional additives, 11 parts of inorganic fillers, 1.5 parts of rare earth fluoride nanofibers; the film-forming copolymer is 2-trimethylsiloxy-1,1, 1,5,5,5-hexafluoro-2-penten-4-one, (E)-4-(2-cyano-3-ethoxy-3-oxo-1-propene)phenylboronic acid Nacolate, trimethyl 4-phosphocrotonate, N-hydroxysuccinimidyl methacrylate, 1,3-bis(oxiranylmethyl)-5-(2-propenyl)- 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione is prepared by free radical copolymerization.

[0033] The inorganic filler is titanium dioxide; the functional auxiliary agent includes a defoamer, a dispersant, and a wetting agent; the mass ratio of the defoamer, ...

Embodiment 3

[0038] A self-cleaning flame-retardant and corrosion-resistant fluorosilicone powder coating is characterized in that it is made of the following components in parts by weight: 55 parts of film-forming copolymers, 6 parts of amino-terminated hyperbranched compound quaternary ammonium salts, lignin sulfonate 2 parts of acid, 0.15 parts of phosphorus pentoxide, 5 parts of functional additives, 13 parts of inorganic fillers, 2 parts of rare earth fluoride nanofibers; the film-forming copolymer is 2-trimethylsiloxy-1,1, 1,5,5,5-hexafluoro-2-penten-4-one, (E)-4-(2-cyano-3-ethoxy-3-oxo-1-propene)phenylboronic acid Nacolate, trimethyl 4-phosphocrotonate, N-hydroxysuccinimidyl methacrylate, 1,3-bis(oxiranylmethyl)-5-(2-propenyl)- 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione is prepared by free radical copolymerization.

[0039] Described inorganic filler is talcum powder; Described functional aid comprises defoamer, dispersant, wetting agent; The mass ratio of described defoamer, dispersant...

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Abstract

The invention discloses a self-cleaning flame-retardant corrosion-resistant fluorine-silicon powder coating. The coating is prepared from the following components in parts by weight: 50-60 parts of afilm-forming copolymer, 4-8 parts of amino-terminated hyperbranched compound quaternary ammonium salt, 1-3 parts of lignosulfonic acid, 0.1-0.2 part of phosphorus pentoxide, 3-7 parts of a functionalaid, 10-15 parts of an inorganic filler and 1-3 parts of rare earth fluoride nanofibers, wherein the film-forming copolymer is prepared from 2-trimethylsiloxy-1,1,1,5,5,5-hexafluoro-2-penten-4-one, (E)-4-(2-cyano-3-ethoxy-3-oxo-1-propenyl)phenylboronic acid pinacol ester, trimethyl 4-phosphonobutenoate, N-hydroxysuccinimide methacrylate and 1,3-bis(oxiranylmethyl)-5-(2-propenyl)1,3,5-triazinyl-2,4,6(1H,3H,5H)-trione through a free radical polymerization reaction. The powder coating disclosed by the invention is remarkable in self-cleaning effect, good in performance stability, corrosion resistance, weather resistance, wear resistance, film-forming property and flame retardance, excellent in bonding property with a base material, superior in comprehensive performance, and safe and environment-friendly to use.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a self-cleaning flame-retardant and corrosion-resistant fluorosilicon powder coating and a preparation method thereof. Background technique [0002] In recent years, with the continuous development of my country's economy, the building and its supporting decoration industry have simultaneously entered an era of unprecedented rapid development. Coatings, as a common building decoration material, have been more and more widely used in industry, agriculture, national defense, scientific research and people's lives. There are more and more varieties of coatings on the market, and their quality and performance are constantly improving. Many functional coatings It has gradually occupied a large market share and has been sought after by consumers. It has become the "darling" of the coatings market at present and in the future, and has very high market potential. [0003] Paint is a ki...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/14C09D5/18C09D5/08C09D5/14C09D7/61C09D7/65C08F220/36C08F230/08C08F230/06C08F230/02C08F226/06
CPCC09D143/04C09D5/18C09D5/08C09D5/14C09D7/61C09D7/65C09D7/70C08F220/36C08K2201/011C08L2201/02C08L2205/03C08F230/085C08F230/065C08F230/02C08F226/06C08L97/005C08L79/00C08K13/04C08K7/04C08K3/32
Inventor 不公告发明人
Owner 东莞市正荣实业有限公司
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