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77 results about "Methyl radical" patented technology

Methyl (also systematically named trihydridocarbon) is an organic compound with the chemical formula CH•₃ (also written as [CH₃]•). It is a metastable colourless gas, which is mainly produced in situ as a precursor to other hydrocarbons in the petroleum cracking industry. It can act as either a strong oxidant or a strong reductant, and is quite corrosive to metals.

Organic working fluids

The present invention provides an improved, commercially available organic working fluid, which is operable under a broad range of temperatures, is thermally stable, has a high auto-ignition temperature, low freezing point and high critical temperature and is benign to the environment, and safe for human use. Such an organic working fluid is useful in organic Rankine cycle (ORC) power plants or units and other systems of the like; as an intermediate fluid for heat-recovery wherein heat from various heat sources is transferred using the intermediate fluid to a further working fluid and converted into work, and the intermediate fluid is also exploited to produce electricity. Such organic working fluids are also operable as heat transfer fluids either in ORC power plants or units or in other heat transfer systems. For this purpose the present invention presents a working fluid comprising at least one highly branched, heavy iso-paraffin hydrocarbons, or a mixture of two or more of such hydrocarbons. Preferably, at least one highly branched iso-paraffin hydrocarbon is present as the major component (i.e. at least 50% by volume) in the working fluid. A preferred sub-class of the class of the branched iso-paraffins which are suitable to be incorporated in organic working fluids of the present invention includes 8 to 20 carbon atom-containing hydrocarbons having at least one methyl radical (CH3) arranged to achieve a highly stable compound.
Owner:ORMAT TECH INC

Semiconductor device and manufacturing method thereof

A semiconductor device includes a metal wiring provided on a semiconductor substrate. The device further includes an anti-metal diffusion film formed on the metal wiring, a buffer layer which is formed on the anti-metal diffusion film and includes at least a silicon-methyl radical bond and a silicon-oxygen bond, and a low-dielectric constant film layer which is formed on the buffer layer and includes at least the silicon-methyl radical bond and the silicon-oxygen bond, wherein the silicon-methyl radical bonding density of the buffer layer is less than the silicon-methyl radical bonding density of the low-dielectric constant film layer.
Owner:KK TOSHIBA

Preparation of organosilicon compounds containing alpha, beta-unsaturated carboxylic acids

Organosilicon compounds (P) containing alpha,beta-unsaturated carboxylic acid radicals, of the general formula (1)are prepared by a process in which, in a first step, organosilicon compounds (H) containing hydrogen atoms bonded directly to silicon are reacted with olefinically unsaturated compounds (U) containing a terminal double or triple bond, of the general formula (2)in the presence of metals or compounds from the platinum group as catalyst, to give organosilicon compounds (E) containing radicals of the general formula (3)and, in a second step, H-Z compounds are eliminated from organosilicon compounds (E), whereA is a divalent organic radical,OMEGA is a monovalent organic radical containing a terminal double or triple bond,R is an H atom or a methyl radical, andZ is Cl, I, Br or 4-methyltoluenesulfonyl.
Owner:WACKER CHEM GMBH

Optically active aliphatic alcohols and their use as perfuming ingredients

The optically active compounds of formula wherein R1 represents a hydrogen atom or a methyl radical, or of formula are useful as perfuming ingredients for the preparation of perfuming compositions and perfumed articles to which they impart woody-amber notes.
Owner:FIRMENICH SA

Method for preparing 3-methyl-4-nitrobenzoic acid by oxidizing with nitric acid

InactiveCN104447348AReasonable control of reaction temperatureReasonable control of reaction pressureOrganic chemistryOrganic compound preparationChromium trioxideReaction temperature
The invention relates to a method for preparing 3-methyl-4-nitrobenzoic acid by oxidizing with nitric acid. The method comprises the steps of carrying out oxidation reaction, neutralizing, extracting, decolorizing and acidifying, wherein diluted nitric acid serves as an oxidant, and 2,4-dimethyl-nitrobenzene serves as a basic raw material. The feed ratio, the reaction temperature, the reaction pressure and the reaction time are controlled reasonably, thus the problems of low reaction conversion rate and generation of many by-products are solved. Because the diluted nitric acid serves as the oxidizing agent and replaces potassium permanganate, potassium dichromate, chromium trioxide and other strong oxidizing agents which are high in cost and are difficult to recover, and the generated waste acid can be recycled, the cleanness of industrial synthesis reaction can be improved, and the pollution to environment can be reduced. The method provided by the invention has the advantages that the reaction yield is improved to over 50% from the initial 27%, the reaction condition is mild, the production and operation safety is high, the reaction equipment is simple, and the raw materials including nitric acid and 2,4-dimethyl-nitrobenzene are wide in supply and low in cost and are suitable for large-scale industrial production.
Owner:GANSU YINGUANG CHEM IND GRP CO LTD

Thermal desorption, gas-phase separation and thermal cracking system based on ethylation derivation of methyl mercury

The invention discloses a thermal desorption, gas-phase separation and thermal cracking system based on ethylation derivation of methyl mercury, comprising a thermal desorption part, a gas-phase separation part, a thermal cracking part, a gas flowmeter, a Teflon FEP pipeline and a pressure regulating and temperature control switch chamber, wherein the thermal desorption part comprises a thermal desorption heater strip switch, a thermal desorption heater strip time control switch, a thermal desorption heater strip pressure regulator, a pressure regulating knob of the thermal desorption heater strip pressure regulator, a thermal desorption heater strip and a Tenax adsorption pipe; the gas-phase separation part comprises a heater jacket, a heater jacket switch, an OV-3 packed column and a heater jacket temperature control plate; and the thermal cracking part comprises a thermal cracking heater strip switch, a thermal cracking heater strip time control switch, a thermal cracking heater strip pressure regulator, a pressure regulating knob of the thermal cracking heater strip pressure regulator, a thermal cracking heater strip and a quartz pipe. The system realizes the aim of integration of thermal desorption, gas-phase separation and thermal cracking devices, and simultaneously, each part can be individually operated, thereby saving the analysis time, having low manufacturing cost and greatly reducing experiment cost.
Owner:OCEAN UNIV OF CHINA

Bi-radical compound composed of triaryl methyl radical and nitroxide radical and salt thereof and preparation method and application of bi-radical compound composed of triaryl methyl radical and nitroxide radical and salt thereof

ActiveCN108794510AExcellent frequency matchingHigh CE efficiencyOrganic chemistryWater resource assessmentMagic angle spinningSolubility
The invention provides a bi-radical compound composed of a triaryl methyl radical and a nitroxide radical and salt thereof and a preparation method and application of the bi-radical compound composedof the triaryl methyl radical and the nitroxide radical and the salt thereof. A structural formula of the bi-radical compound is as shown in the formula 1; the formula is shown in the description; thepreparation method comprises the steps that a compound A1 and a compound A2 are subjected to acid amide condensation reaction to obtain a compound A3; the compound A3 and a compound A4 are subjectedto acid amide condensation reaction to obtain the bi-radical compound and the salt thereof. The portion, provided with both the nitroxide radical and the triaryl methyl radical, of a bi-radical polarization agent has the following advantages that the frequency matching ability is better, and the CE efficiency is higher; under a magic angle spinning condition, a depolarization effect does not exist, and a high field DNP enhancing effect is better; exchange interaction is stronger; the water solubility is good, so that the DNP enhancing multiple is high; by modifying R1, R2, R3, R4, R5 and R6 groups, exchange interaction can be improved moderately, bi-radical relaxation time can be prolonged moderately, and the bi-radical water solubility can be improved moderately, so that the DNP propertyof the polarization agent is improved.
Owner:TIANJIN MEDICAL UNIV

Multi-bed reaction device for preparing hydrogen by sodium borohydride alcoholysis

The invention discloses a multi-bed reaction device for preparing hydrogen by sodium borohydride alcoholysis. The multi-bed reaction device comprises a sodium borohydride storage tank, a flow controller, a sprayer, a catalyst reaction bed, a heat exchanger and a product recovery tank; the sodium borohydride storage tank is used for storing an alkaline sodium borohydride methanol solution; the flow controller is used for adjusting the flow velocity and flow rate of the solution; the sprayer is arranged at the top of the hydrogen production reaction tank; the catalytic reaction bed comprises at least two layers of catalyst reaction beds; the heat exchanger is used for regulating and controlling the temperature of the reaction tank. The product recovery tank is placed at the bottom of the reaction tank to collect the reactants sodium tetramethylborate for following recovery and reuse. The multi-bed reaction device is capable of improving the utilization rate of the reactants and realizing the precise control over hydrogen production quantity. The contact of the reactants with the catalyst is expanded, the liquid-solid separation is more thorough, the influence of concentration difference gradient is eliminated, furthermore the catalyst utilization rate is improved, and the cost of precious metal is reduced.
Owner:XUZHOU NORMAL UNIVERSITY

Laser soldering flux for Cu-Mg-Sn-Fe composite nanomaterial and preparation method of laser soldering flux

The invention discloses laser soldering flux for a Cu-Mg-Sn-Fe composite nanomaterial and a preparation method of the laser soldering flux. The laser soldering flux is prepared from, by weight, pure water, polyoxyethylene(4)C8alcohol ether, polyoxyethylene polyoxypropylene ether carboxylate of fatty alcohol, N-methyl(13C)-N-nitroso para toluene sulfonamide, 3-nitrophthalimide, 1-hydroxy-4-(para-toluene amino)anthraquinone, 1-amino-2-[4-[(hexahydro-2-oxo-1H-azepin-1-yl) methyl]phenoxy]-4-hydroxy-9,10-anthraquinone, methoxybenzyl alcohol and mercury nanoparticles. The laser soldering flux has the beneficial effects that according to the method, welding strength can be improved, welding stress and welding deformation are greatly reduced, the process is stable, the application range is wide, cooling is fast, the effect is good, and different welding requirements are met.
Owner:XUZHOU UNIV OF TECH
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