The invention relates to a method for separating solvents after a chlorination and neutralization reaction of sucralose. The method comprises the following steps: filtering a neutralized solution obtained after chlorination and neutralization, pumping the filtered neutralized solution into an extraction kettle, adding 10# industrial oil used as an extractant to extract the solvent trichloroethaneand DMF and make the solvents enter a supernatant, carrying out secondary reduced-pressure rectification on the supernatant, respectively separating the trichloroethane and DMF by using a boiling point difference, decolorizing high-boiling point industrial oil obtained after the secondary rectification with activated carbon to make the decolorized high-boiling point industrial oil directly reused,and directly reusing the trichloroethane and DMF obtained after the two-stage rectification in chlorination; and directly adding water to obtained lower oil to dissolve the lower oil, decolorizing and filtering the obtained solution, adding ethyl acetate, and performing freezing crystallization to obtain crude sucralose-6-acetate. The method has the advantages of simplicity, avoiding of the process of adding water to carry away the solvents during solvent recovery in traditional processes, reduction of the solvent recovery difficulty, improvement of the solvent recovery efficiency, energy consumption saving, great reduction of the production cost, and reduction of pollution.