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92 results about "Ferrous Compounds" patented technology

Inorganic or organic compounds that contain divalent iron.

Method for synthesizing ferrous aluminum spinel

ActiveCN101823872AAvoid volume effectLower oxygen partial pressureFireproofingSpinel
The invention relates to a method for synthesizing ferrous aluminum spinel, belonging to the technical field of fireproofing materials. The method comprises the following steps of: mixing ferrous compound and aluminiferous compound according to the mol ratio of Fen<+> to Al<3+> of 1:2, additionally adding a binding agent accounting for 1-6 percent of the weight of the mixture, mixing, pressing, drying and sintering under the nitrogen atmosphere at the temperature of 1300-1700 DEG C, and keeping the temperature for 2-12 hours. The invention has the advantages of high synthetic purity, simple process and easy actualization.
Owner:SHANDONG SHENGCHUAN CERAMICS +3

Low self-discharge ferrous electrode material

The invention provides a low self-discharge ferrous electrode material. The ferrous electrode material is characterized by consisting of an active substance and an additive, wherein the composition ofthe active substance is ferrum or ferrous compounds including one or more of Fe3O4, Fe(OH)2, Fe(OH)3, Fe2O3, reduced ferrous powder and carbonyl ferrous powder; and the additive comprises: 1) 0.02 to0.15 percent of indium or indium compounds including one or more of In, In2O3, In2(SO4)3, In(OH)3, InCl3 and the like; 2) 2 to 8 percent of stannum or stannum compounds including one or more of Sn, SnO, SnO2, SnCl2, SnCl4 and stannate; 3) 1 to 7 percent of bismuth or bismuth compounds including one or more Bi, Bi2O3, Bi(NO3)3 and the like; and 4) 5 to 10 percent of graphite powder. The ferrous electrode material has the advantages that: 1) no toxic heavy metals (such as Hg, Cd, Pb and the like) are added, so the electrode material is an environment-friendly electrode material 2) the cost foran electrode is quite low; and 3) the self-discharge rate of the electrode is less than 20 percent at a temperature of 20 DEG C after 28 days. The material is used for manufacturing environment-friendly ferrum-nickel storage batteries.
Owner:宝生集团有限公司

Fe3O4/TiO2 composite nano-particles as well as preparation method and application thereof in magnetic resonance imaging contrast medium

The invention relates to Fe3O4 / TiO2 composite nano-particles as well as a preparation method and an application thereof in a magnetic resonance imaging contrast medium. The preparation method of the Fe3O4 / TiO2 composite nano-particles comprises the following steps: dissolving ferric compound and ferrous compound in the aqueous solution of reducing acid; and dropwise adding a titanic salt solutioninto the solution so as to prepare the sol of Fe3O4 / TiO2 composite nano-particles after the reaction. Compared with the prior art, the preparation method of Fe3O4 / TiO2 composite nano-particles provided by the invention is simple to operate and low in preparation cost, and does not need N2 (nitrogen) protection during the reaction; and the product has the advantages of uniform particle size distribution, controllable size, good water solubility and biocompatibility, no toxicity and the like. As the Fe3O4 / TiO2 composite nano-particles prepared by the preparation method provided by the inventionare a composite nano-material with superparamagnetism and optical catalytic activity, the Fe3O4 / TiO2 composite nano-particles can be applied to the magnetic resonance imaging contrast medium.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI

Preparation and recovery methods for magnetic clay adsorption material

The invention provides preparation and recovery methods for a magnetic clay adsorption material. The preparation process comprises adding a strong base substance into an aqueous solution of a mixture of inorganic ferric / ferrous compounds under the circumstances of nitrogen protection and sufficient stirring, so as to prepare a magnetic nanoparticle; adding an ethanol solution of a surfactant into an aqueous solution of the prepared magnetic nanoparticle, and fully stirring and mixing for reaction; fully mixing a bentonite suspension fully swelled by water with the surface-functionalized magnetic nanoparticle for reaction; and performing sufficient magnetic separation on the reaction product and washing off superfluous metal and nonmetal ions, so as to obtain the magnetic clay material. The magnetic clay material adsorbing dye pollutants can be reestablished and reused through gamma radiation of a 60 Co radioactive source. The provided preparation method is simple, and the prepared magnetic clay absorption material is convenient to use, high in adsorption efficiency, and repeatedly reusable.
Owner:NANJING UNIV OF AERONAUTICS & ASTRONAUTICS

Preparation of ferrous compound in polyhydroxy structural state and application of ferrous compound in wastewater reduction pretreatment

The invention relates to preparation of a ferrous compound in a polyhydroxy structural state and an application of the ferrous compound in wastewater reduction pretreatment. The preparation method comprises the following steps: dissolving a certain amount of ferrite in water without dissolved oxygen; and then gradually dropping oxygen-free alkaline solution in the obtained solution while stirringcontinuously, and generating structural state ferrous hydroxy complex (FHC) by controlling the molar ratio of ferrous ions to hydroxyls. The FHC prepared by the invention has high reduction activation and high reaction rate with pollutants and can fast reduce and convert harmful and poisonous pollutants in wastewater; and dissolved ferrous state is converted to structural ferrous state so as to obviously increase the reduction performance of the ferrous state. The FHC is used in the wastewater reduction pretreatment; and the scope of application of pH is wide, and the FHC has good effect whenthe pH value is 4-10. In addition, the FHC is more convenient to add compared with catalyzed iron filler; the wastewater treatment process is easy to operate, manage and maintain, and the cost is low; and the FHC is suitable for the large-scale reduction pretreatment of industrial wastewater.
Owner:TONGJI UNIV

A method for simultaneously removing ammonia nitrogen and nitrate nitrogen from a water body

A method for simultaneously removing ammonia nitrogen and nitrate nitrogen from a water body is disclosed. The method includes subjecting the water body containing ammonia nitrogen and nitrate nitrogen to oxidation-reduction treatment by adopting an iron catalyst under functions of anaerobic ammoxidation microbes, iron autotrophic denitrification microbes and iron-reduction ammoxidation microbes.The iron catalyst includes one or a plurality of elementary iron, a ferrous compound and a ferric compound. The catalytic treatment is performed in an anaerobic environment. The anaerobic ammoxidationmicrobes, iron autotrophic denitrification microbes and iron-reduction ammoxidation microbes provide reaction functional microbes for anaerobic ammoxidation, iron autotrophic denitrification and iron-reduction ammoxidation, allow oxidation-reduction treatment of the ammonia nitrogen and nitrate nitrogen to be performed stably and continuously under the premise of not continuously adding the catalyst, and can completely convert the ammonia nitrogen and nitrate nitrogen into nitrogen without a byproduct. The method is free of secondary pollution.
Owner:SUZHOU UNIV OF SCI & TECH

Graphene filter composite membrane and preparation method thereof

ActiveCN107008156AIncreased degradation rateSolve the problem of inability to reduce the toxicity of refractory pollutantsSemi-permeable membranesWater treatment compoundsCross-flow filtrationChloride
The invention provides a preparation method of a graphene filter composite membrane. The preparation method comprises the following steps of: filtering carboxylated graphene oxide to a membrane supporting layer by means of a suction filtration method or a cross flow filtration method to form a composite membrane supporting layer; and filtering a ferric chloride solution by using the formed composite membrane supporting layer, and performing reduction to form an electro-Fenton catalytic layer comprising a ferrous compound to prepare the graphene filter composite membrane. As the electro-Fenton catalytic layer comprises the ferrous compound which has a certain interception performance on refractory pollutants and can decompose the refractory pollutants in situ, the problem that the toxicity of the refractory pollutants cannot be reduced by means of a membrane technology is solved, and the membrane pollution is alleviated. Meanwhile, as the membrane supporting layer is arranged below the electro-Fenton catalytic layer, and in a process of filtering secondary effluent, the refractory pollutants can be enriched to a certain degree, so that the degrading rate of the electro-Fenton catalytic layer on the refractory pollutants can be further increased.
Owner:RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI

Positive pole lithium iron phosphate/carbon composite material for low-temperature battery and preparation method of composite material

The invention discloses a preparation method of a positive pole lithium iron phosphate / carbon composite material for a low-temperature battery. The preparation method comprises the following steps: by adopting a ferrous compound as a raw material, and weighing the ferrous compound, a lithium compound and a phosphorus compound according to the mole ratio of Fe:Li:P=(0.98-1):(1-1.02):1; respectively dissolving or dispersing in deionized water; adding to a liquid-phase reducing agent with moderate volume according to a certain sequence; carrying out reflux reaction at specific temperature; carrying out solid-liquid separation to obtain lithium iron phosphate precursor; then calcining under the protection of inert gas to prepare the LiFePO4 / C composite positive pole material. Compared with other methods, the preparation method disclosed by the invention has the advantages of simple process equipment, moderation in condition, completeness in precursor crystallization, great shortening of high-temperature calcination time, great reduction of energy consumption, fine lithium iron phosphate particle diameter and more excellent normal-temperature discharge property and low-temperature charge-discharge property.
Owner:CHENGDU SCI & TECH DEV CENT CHINA ACAD OF ENG PHYSICS

Electrolyzing solution, method and application for micro-arc oxidation

The invention discloses an electrolyzing solution, method and application for micro-arc oxidation. The electrolyzing solution for micro-arc oxidation comprises phosphates with the final concentration being 5-50 g / L, iron containing compounds with the final concentration being 1-15 g / L and complexing agents with the final concentration being 1-10 g / L, and distilled water serves as solvents. The iron containing compounds are ferrous compounds and / or ferric compounds. According to the electrolyzing solution for micro-arc oxidation, the phosphates, the iron containing compounds and the complexing agents are dissolved in water, not only is the using requirement of the electrolyzing solution for the micro-arc oxidation met, but also the phosphates subjected to phosphating are introduced into the electrolyzing solution, and phosphating and the micro-arc oxidation are combined, so that an obtained film layer subjected to the micro-arc oxidation through the electrolyzing solution has better density, and accordingly corrosion resistance performance of a treated workpiece is improved.
Owner:PEKING UNIV SHENZHEN GRADUATE SCHOOL

Ferrous ion reduction and catalytic oxidation cooperation for reinforcing waste water biological treatment technology

The invention relates to ferrous ion reduction and catalytic oxidation cooperation for reinforcing waste water biological treatment technology, and is suitable for processing difficultly degraded industrial waste water, the waste water biological treatment technology comprises four steps of preparation of a structural state ferrous compound, reduction treatment, catalytic oxidation treatment and biochemical treatment. Compared with the prior art, the ferrous reduction function can be fully performed, simultaneously, the catalysis performance of the ferrous reduction product can be further used, a few of hydrogen peroxide and a reinforcement material can be added, catalytic oxidation is carried out to remove a part of difficultly degraded pollutant, waste water biodegradability is further enhanced, the biological treatment technology can be coupled, so that the thorough treatment of waste water is realized. The waste water biological treatment technology has the advantages of wide water quality adaptation scope, high efficiency economy and simple utility.
Owner:TONGJI UNIV

Three-layer nuclear-shell lithium-ion battery positive composite material and preparation method thereof

The invention relates to a three-layer nuclear-shell lithium-ion battery positive composite material which comprises a spherical lithium iron phosphate inner layer, a carbon layer which wraps the lithium iron phosphate inner layer, and a silicon dioxide layer which wraps the carbon layer. The preparation method of the composite material comprises the following steps of: mixing and dissolving a lithium compound, a ferrous compound and a phosphorous compound for mixing with a template guiding agent and a carbon source, the mixture, and placing the mixture after ultrasonic dispersing into a water heating kettle for reaction under inert gas; washing reactants respectively through deionized water and absolute ethyl alcohol, and drying the reactants to obtain a spherical precursor; adding the spherical precursor under the protection of nitrogen into an alcohol aqueous solution, and then adding TEOS (tetraethyl orthosilicate) for reaction to obtain turbid liquid; filtering the turbid liquid, and drying in a spraying manner to obtain the composite material. In the synthesis process of the material, the template guiding agent is adopted, so that the three-layer nuclear-shell lithium-ion battery positive composite material with a uniform spherical shape, high compactness density and an excellent electrochemical performance can be obtained.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY

Process for producing potassium permanganate doped potassium ferrate

The invention discloses a method for preparing potassium permanganate-doped potassium ferrate. The method comprises the following steps: firstly, mixing a ferrous compound and a stabilizer by the proportion of Fe and the stabilizer; secondly, dissolving the mixture in a potassium hydroxide solution; thirdly, stirring, adding an oxidizer to the potassium hydroxide solution by a certain proportion of Fe and the oxidizer at the temperature controlled within a certain range, reacting for a certain time, separating the purple suspended solid product prepared from the reaction, decompressing and filtering; fourthly, mixing the purple solid product with the mixed solution of potassium hydroxide and potassium permanganate in a certain proportion, stirring and separating the purple solid to obtain the purple solid product; and fifthly, rinsing the purple solid product with cyclohexane, absolute alcohol and ether respectively, decompressing and filtering, and vacuum drying until the weight is constant to obtain the potassium ferrate solid. The invention has the advantages that the purity of synthesis is high, the thermal stability of the synthesis is high, the purity of potassium ferrate is higher than 98%, the content of the potassium ferrate is higher than 96%; the obtained potassium ferrate has good electrochemical performance; and the conservation rate of the charge/discharge cycle discharge capacity is up to 90.5%.
Owner:STATE GRID CORP OF CHINA +1

Iron oxide pigment and its production method

The invention discloses an iron oxide pigment and its production method. The method includes steps of 1) preparing reaction fluid, wherein the reaction fluid contains complexing agent and inert gas and its pH value is 7.0-13.0; adding scrap iron or ferrous compound or ferric ion compound therein; after dissolving, separating impurities to obtain iron solution; 2), charging oxygen gas in the iron solution so that the ferric ion in the iron solution is oxidized to be iron oxide yellow, iron oxide red or iron oxide black sediment; separating to obtain iron oxide pigment and reaction mother liquor, wherein the complexing agent is one or two of methylamine, ethylamine, ethylenediamine, propylene amide, ethanolamine, imidazole, diethylenetriamine, triethylenetetramine, ethylenediamine tetraacetic acid, ethylene diamine diacetate, nitrilotriacetic acid, glutamic acid, valine, histidine, proline, aspartic acid, alanine, serine, phenylalanine, arginine, threonine, glycine, lysine, asparaginate and glutamine.
Owner:北京中金瑞丰环保科技有限公司
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