The invention discloses a method for co-production of feed
manganese sulfate by using
wastewater of crude
indium production. According to the method, on the basis of production of feed
manganese sulfate through a wet method, the influence of excessive
sulfuric acid and
heavy metals including
arsenic,
cadmium and the like in the
wastewater of the crude
indium production through a wet method on the environment is thoroughly eliminated while the feed
manganese sulfate is produced, so that the production of crude
indium and the feed manganese sulfate through the wet method achieves comprehensive and full utilization of wastes, and the
pollution caused by waste
acid water containing
heavy metals to the environment is thoroughly eliminated. The method comprises the steps of 1, performing leaching reaction on manganese ash in a leaching tank by using indium preparation
wastewater; 2, performing pressure
filtration; 3, adjusting the pH value of the filtrate to 4-4.5, and then pressing liquid; 4, adding
barium sulfide to improve the pH value of a
stock solution to 5-5.4, and then filtering; 5, cooling and standing the
stock solution, adding an SDD (
sodium dimethyl
dithiocarbamate) solution and a flocculating agent, then performing pressure
filtration, concentrating the filtrate, performing evaporative
crystallization, and
drying to obtain a feed manganese sulfate product. By adopting the method, the indium preparation wastewater and waste residues causing environmental
pollution can be fully and comprehensively used, and a
raw material for producing manganese sulfate is provided, so that the method is favorable for reducing the production cost and protecting the
ecological environment.