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35results about How to "Has potential application value" patented technology

Preparation method for cation nanocrystalline cellulose enhanced papermaking surface sizing agent

The invention relates to a preparation method for a cation nanocrystalline cellulose enhanced papermaking surface sizing agent.According to the preparation method, firstly, edible corn starch is gelatinized and compounded with cation styrene-acrylic emulsion; secondly, cation nanocrystalline cellulose is used for enhancing the composite emulsion; lastly, a Mayer coating machine is used for conducting surface sizing on fine dried noodle cardboard paper.According to the prepared surface sizing agent, the edible corn starch and the nanocrystalline cellulose are used as main raw materials, application of synthetic latex cation styrene-acrylic emulsion is omitted, and this conforms to the strategy of sustainable development.The cation nanocrystalline cellulose enhanced papermaking surface sizing agent is simple in preparation process and good in flowing property, a good barrier property is given to the paper, and meanwhile the mechanical property and surface property of the paper can be improved.
Owner:ZHEJIANG SCI-TECH UNIV

Amido reinforced graphene film, nitrogen doped graphene film and preparation method thereof

The present invention discloses an amido reinforced graphene film, a nitrogen doped graphene film and a preparation method thereof. The method includes the following steps: extruding a graphene oxide solution by a device with an in-line die orifice nozzle; staying, solidifying and reducing in a mixed liquid of liquid amine solidification liquid and a reducing agent for self-assembly into a film, and drying, wherein the temperature of the mixed liquid is 60-95 DEG C, and the stay time is more than 0.5 h. The method has the wide raw material sources and low cost; the preparation method uses graphene oxide solution as raw material, realizes solidification, reduction and self-assembly into amido reinforced graphene film through one step, has the advantages of low reaction temperature, simple operation, green and environment-friendliness, and can realize large-scale continuous preparation. The amido reinforced graphene film prepared by the method has good strength and toughness, excellent thermal conductivity and electrical conductivity, and broadens the scope for subsequent application. The amido reinforced graphene film can increase the electrical conductivity and mechanical properties of the film.
Owner:SHANGHAI INST OF APPLIED PHYSICS - CHINESE ACAD OF SCI

Anionic N-substituted aniline ionic liquid and preparation method thereof

The invention discloses an anionic N-substituted aniline ionic liquid. The anion of the ionic liquid contains an N-substituted aniline structure, and preferably the structure of the anionic N-substituted aniline ionic liquid is shown in the formula (I). The anionic N-substituted aniline ionic liquid is obtained by making an aqueous solution of a cationic halide salt (AX) pass through anion exchange resin and then carrying out neutralization reaction, or directly carrying out ion exchange. The anionic N-substituted aniline ionic liquid not only has the properties and application of general ionic liquids such as serving as a reaction medium, an additive for polymer materials and the like, but also can act as a corrosion inhibitor to slow the corrosion of metals by acidic media, and even canbe used as a reaction monomer for preparing a polyionic liquid type polyaniline derivative through auto-oxidation polymerization or oxidative copolymerization with aniline, or for preparing a crosslinked polyionic liquid type polyaniline derivative further through other polymerization means such as radical polymerization and the like.
Owner:BEIJING NORMAL UNIVERSITY

Method for classifying and extracting xylogen and xylo-oligosaccharide in papermaking black liquid

The invention provides a method for classifying and extracting xylogen and xylo-oligosaccharide in papermaking black liquid. The method mainly comprises the following steps: diluting papermaking blackliquid, regulating the pH value, ageing, standing, and performing centrifugal separation to obtain centrifugate and a solid precipitate; performing rotary evaporation concentration on the centrifugate, dripping ethanol to precipitate, and performing centrifugal separation to obtain solid xylo-oligosaccharide; purifying and dissolving the solid precipitate with a methanol / acetone mixed solution; dripping an ethyl acetate solvent to precipitate, and performing centrifugal separation to obtain xylogen F1 and centrifugate; performing rotary evaporation concentration on the centrifugate, drippingan ethyl acetate / petroleum ether mixed solution to precipitate, and performing centrifugal separation to obtain xylogen F2 and centrifugate; and performing rotary evaporation concentration on the centrifugate, dripping petroleum ether to precipitate, and performing centrifugal separation, thereby obtaining xylogen F3 and xylogen F4 in the centrifugate. The method disclosed by the invention is capable of realizing classification and separation of xylogen and recycling of the xylo-oligosaccharide in bagasse papermaking black liquid, is wide in application range, simple in process and reliable intechnology and has actual application and popularization value.
Owner:GUANGXI UNIV

Cationic N-substituted aniline ionic liquid and preparation method thereof

The invention discloses a cationic N-substituted aniline ionic liquid, wherein an N-substituted aniline structure is contained in positive ions, and preferably, the structure of the cationic N-substituted aniline ionic liquid is shown as formula (I). A preparation method of the cationic N-substituted aniline ionic liquid comprises the following steps: firstly preparing N-phenylethanolamine hydrobromide, then preparing N-phenylethanolamine bromide from N-phenylethanolamine hydrobromide, and finally reacting N-phenylethanolamine bromide with compounds as shown in formulas (II-1) to (II-14) to obtain the cationic N-substituted aniline ionic liquid. The cationic N-substituted aniline ionic liquid has the properties and applications of common ionic liquid (such as serving as a reaction medium,an additive of a polymer material and the like), can be used as a monomer, can also be used as a reaction monomer to prepare ionic liquid polyaniline derivative through self oxidative polymerization or oxidative copolymerization with other monomers, and can also be combined with other polymerization means (such as free radical polymerization and the like) to prepare ionic liquid polyaniline derivatives and compounds of the ionic liquid polyaniline derivatives and other polymers.
Owner:BEIJING NORMAL UNIVERSITY

Nitrogen-doped graphene-metal nanoparticle film and preparation method thereof

The invention discloses a nitrogen-doped graphene-metal nanoparticle film and a preparation method thereof, and the preparation method comprises the following steps: (1) uniformly mixing a graphene oxide solution, metal nanoparticles and a water-soluble amine cross-linking agent to obtain a mixture; wherein the mass ratio of the graphene oxide to the metal nanoparticles is (1: 0.01)-(1: 5); (2) coating the mixture obtained in the step (1) to form a film, and drying at 20-95 DEG C to obtain an amino cross-linked graphene oxide-metal nanoparticle film; and (3) carrying out heat treatment on the amino cross-linked graphene oxide-metal nanoparticle film obtained in the step (2) under the protection of inert gas to obtain the nitrogen-doped graphene-metal nanoparticle film. In the graphene oxide solution, the metal nanoparticles and the water-soluble amine cross-linking agent, a graphene oxide solution coating method is adopted, solidification and self-assembly of the amino cross-linked graphene oxide-metal nanoparticle film can be achieved at the same time in one step, and the method is low in reaction temperature, easy to operate, environmentally friendly, capable of achieving large-scale preparation, simple, controllable and suitable for industrial production. The single condition is easy to operate.
Owner:杭州嘉悦智能设备有限公司

Method for preparing hydrogen, oxygen and hydrocarbon mixed gas through reaction of rare earth diboron dicarbon material and water

The invention relates to the field of high-performance ceramic materials, in particular to a method for preparing hydrogen, oxygen and hydrocarbon mixed gas through reaction of a rare earth diboron dicarbon material and water. The rare earth oxide powder, boron carbide powder and graphite powder are used as raw materials to prepare rare earth diboron dicarbon powder, the raw material powder in a proper proportion is mixed for 6-12 hours through a physical and mechanical method, dried, sieved and then put into a graphite crucible, then the graphite crucible is put into a sintering furnace with high-purity argon to be sintered, the heating rate is 5-20 DEG C / min, the sintering temperature is 1800-2200 DEG C, and heat preservation is conducted for 1-8 hours. The prepared rare earth diboron dicarbon powder is sieved by a 500-mesh sieve and mixed with deionized water at room temperature to prepare mixed gas rich in hydrogen, oxygen, hydrocarbons and the like, the hydrogen and the oxygen are used as main components, the hydrocarbons comprise methane, ethane, ethylene, acetylene, propane, propylene, butylene and the like, and even a small amount of carbon monoxide and carbon dioxide are contained. The reaction process of the material and water and a gas product have potential application value in the industries of energy, chemical engineering, machinery and the like.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

YSZ-based mixed potential type H2S sensor with inverse spinel type Co2SnO4 as sensitive electrode and preparation method of sensor

The invention relates to a YSZ-based mixed potential type H2S sensor with inverse spinel type Co2SnO4 as a sensitive electrode and a preparation method of the sensor, and belongs to the technical field of gas sensors. The sensor is sequentially composed of an Al2O3 ceramic plate with a Pt heating electrode, a YSZ substrate, a reference electrode and the sensitive electrode. The sensor is characterized in that the reference electrode is strip-shaped Pt, the sensitive electrode is strip-shaped Co2SnO4, the two electrodes are symmetrically distributed at the two ends of the upper surface of the YSZ substrate, and the lower surface of the YSZ substrate and the Al2O3 ceramic plate are bonded together. According to the sensor, YSZ is used as an ion conducting layer, and the reverse spinel type Co2SnO4 with high electrochemical catalytic activity is used as the sensitive electrode, so that the gas-sensitive performance of the H2S sensor is effectively improved. In addition, the sensor can show obvious response value difference on exhaled gases of healthy people and simulated ozostomia patients, and shows important application potential in the aspect of ozostomia diagnosis in medical diagnosis and treatment.
Owner:JILIN UNIV

High-density micro-nano coil flexible heterogeneous integration method

The invention discloses a high-density MEMS micro-nano coil flexible heterogeneous integration method. The method comprises the steps: preparing and cleaning a rigid substrate; growing a stripping layer on the rigid substrate; depositing a plurality of layers of MEMS micro-nano coils on the stripping layer, depositing a thin film isolation layer between the MEMS micro-nano coils of adjacent layers, interconnecting the plurality of layers of MEMS micro-nano coils, and depositing a thin film insulation layer on the topmost layer; depositing a thin film seed layer on the thin film insulating layer, and then electroplating a metal stress layer; adjusting the thickness of the metal stress layer, and stripping the MEMS micro-nano coil; integrating the MEMS micro-nano coil and the flexible substrate; sequentially removing the metal stress layer and the film seed layer; forming a hole in the thin film insulating layer; and interconnecting and folding the multiple layers of MEMS micro-nano coils. According to the method, the multiple layers of interconnected MEMS micro-nano coils on the rigid substrate are transferred to the flexible substrate through a controllable stripping method, and the flexible substrate is folded to form a multi-layer stacked structure, so that the number of turns of the coils is greatly increased, and the problem of low output voltage of the MEMS electromagneticenergy collector in a narrow space is solved.
Owner:ZHONGBEI UNIV

Multi-stimulus-response actuating film and preparation and application thereof

The invention relates to a multi-stimulus-response actuating film and preparation and application thereof. The film comprises a carbon nanotube-chitosan film layer and a microfiltration film layer. The preparation method is simple and rapid, large-scale production can be achieved, and the prepared carbon nanotube-chitosan / cellulose acetate fiber filter paper film can have rapid, remarkable and stable deformability under the conditions of electrification, water vapor and infrared light and has important application value in the fields of flexible switches, artificial muscles, soft robots, environmental monitoring and the like.
Owner:DONGHUA UNIV

Antibody type molecular chaperone capable of inhibiting Tau protein from being aggregated

The invention discloses an antibody type molecular chaperone capable of inhibiting Tau protein from being aggregated. The antibody type molecular chaperone scFv T1 can effectively inhibit Tau aggregation, is strong in specificity, high in efficiency and low in toxicity and easy to eliminate in the body, and has the advantages of being humanized, convenient for antibody screening, easy to prepare and the like compared with monoclonal or polyclonal antibody prepared by using the traditional method; compared with common immune globulin, the single-stranded antibody has smaller molecules, is easier to express in animal cells in-vitro or in-vivo cultured in model organism, can break through blood brain barrier, has low toxic and side effects, cannot cause immunoreactions easily, can facilitate the research on cell and animal levels and the clinical treatment and applications of Alzheimer disease, thus providing a new direction for treatment of Alzheimer disease, and having potential application values for treating AD, and good medical application prospects.
Owner:BEIJING NORMAL UNIVERSITY

A method for fractionally extracting lignin and xylooligosaccharides in papermaking black liquor

The invention provides a method for classifying and extracting xylogen and xylo-oligosaccharide in papermaking black liquid. The method mainly comprises the following steps: diluting papermaking blackliquid, regulating the pH value, ageing, standing, and performing centrifugal separation to obtain centrifugate and a solid precipitate; performing rotary evaporation concentration on the centrifugate, dripping ethanol to precipitate, and performing centrifugal separation to obtain solid xylo-oligosaccharide; purifying and dissolving the solid precipitate with a methanol / acetone mixed solution; dripping an ethyl acetate solvent to precipitate, and performing centrifugal separation to obtain xylogen F1 and centrifugate; performing rotary evaporation concentration on the centrifugate, drippingan ethyl acetate / petroleum ether mixed solution to precipitate, and performing centrifugal separation to obtain xylogen F2 and centrifugate; and performing rotary evaporation concentration on the centrifugate, dripping petroleum ether to precipitate, and performing centrifugal separation, thereby obtaining xylogen F3 and xylogen F4 in the centrifugate. The method disclosed by the invention is capable of realizing classification and separation of xylogen and recycling of the xylo-oligosaccharide in bagasse papermaking black liquid, is wide in application range, simple in process and reliable intechnology and has actual application and popularization value.
Owner:GUANGXI UNIV

Metallorganic compound based catalyst used for dissociation of hydrogen

The invention relates to a metallorganic compound based catalyst used for dissociation of hydrogen. The metallorganic compound based catalyst used for dissociation of hydrogen comprises a carrier, anda metal organic compound formed on the surface of the carrier. The metallorganic compound based catalyst possesses excellent activity on hydrogen dissociation at room temeprature, and possesses potential economic application value.
Owner:INST OF PHYSICS - CHINESE ACAD OF SCI +1

Preparation method of symmetric 1,7-dicarbonyl compound

The invention discloses a preparation method of a symmetric 1,7-dicarbonyl compound. The preparation method comprises a step of implementing free radical reaction on dithiocarbonic acid O-alkyl-S-(2-carboxymethyl) ester and allyl sulfone, allyl sulfoxide, allyl sulfide or allyl mercaptan carboxylate to obtain corresponding symmetric 1,7-dicarbonyl xanthate. The preparation method is simple and easily available in raw materials, convenient to operate, and applicable to mass production. The prepared compound can be used as an important organic and pharmaceutical synthesis intermediate, and the like.
Owner:BEIJING UNIV OF CHEM TECH

Novel phase change system of long-chain hydrocarbon and long-chain alkyl polymer

PendingCN114316906AImprove thermal stabilityDifferent Phase Transition Critical PointsHeat-exchange elementsFluid phaseNitrogen gas
The invention discloses a novel long-chain hydrocarbon and long-chain alkyl polymer phase change system. The novel long-chain hydrocarbon and long-chain hydrocarbon polymer phase change system is composed of a phase change material and a phase building agent, the phase change material is a long-chain hydrocarbon polymer or long-chain hydrocarbon, the phase building agent is nitrogen, inert gas or liquid with the boiling point lower than 90 DEG C, and the volume of the phase change material accounts for 1 / 50-1 / 7 of the volume of the phase change system. The original heating rate of the phase change system is greater than 10 DEG C / min, and the initial pressure in the phase change system is 0.5-4 MPa. The novel long-chain hydrocarbon and long-chain alkyl polymer phase change system provided by the invention realizes a violent self-heat-release effect based on liquid-liquid phase change in a high-pressure atmosphere and a relatively high temperature interval, and discovery of the effect has important significance on long-chain molecule phase change research and has potential application value in many fields.
Owner:GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI +1

Zintl-phase thermoelectric material with hexagonal ZrBeSi structure and preparation method of Zintl-phase thermoelectric material

The invention provides a Zintl-phase thermoelectric material with a hexagonal ZrBeSi structure and a preparation method of the Zintl-phase thermoelectric material. The Zintl-phase thermoelectric material has a hexagonal ZrBeSi structure, and the chemical formula of the Zintl-phase thermoelectric material is A2BC2, wherein A is one or a combination of two of elements Eu and Sr, B is an element Zn or a combination of Zn and a first doping element, and C is one or a combination of two of elements Sb and Bi; or the chemical formula of the Zintl-phase thermoelectric material is DEF, wherein D is one or a combination of more than two of elements Eu, Sr, Ba and Ca, B is one or a combination of more than two of elements Cu, Ag or Au, and C is one or a combination of two of elements Sb and Bi. Theinvention discloses a novel thermoelectric material, and the thermoelectric figure of merit of the thermoelectric material is close to the matrix performance of the current mainstream thermoelectric material. In addition, the compound can realize higher thermoelectric figure of merit after doping regulation and control, and has certain potential application value.
Owner:HARBIN INST OF TECH SHENZHEN GRADUATE SCHOOL

A kind of amine-based reinforced graphene film, nitrogen-doped graphene film and preparation method thereof

The present invention discloses an amido reinforced graphene film, a nitrogen doped graphene film and a preparation method thereof. The method includes the following steps: extruding a graphene oxide solution by a device with an in-line die orifice nozzle; staying, solidifying and reducing in a mixed liquid of liquid amine solidification liquid and a reducing agent for self-assembly into a film, and drying, wherein the temperature of the mixed liquid is 60-95 DEG C, and the stay time is more than 0.5 h. The method has the wide raw material sources and low cost; the preparation method uses graphene oxide solution as raw material, realizes solidification, reduction and self-assembly into amido reinforced graphene film through one step, has the advantages of low reaction temperature, simple operation, green and environment-friendliness, and can realize large-scale continuous preparation. The amido reinforced graphene film prepared by the method has good strength and toughness, excellent thermal conductivity and electrical conductivity, and broadens the scope for subsequent application. The amido reinforced graphene film can increase the electrical conductivity and mechanical properties of the film.
Owner:SHANGHAI INST OF APPLIED PHYSICS - CHINESE ACAD OF SCI

Method for preparing comby stannous oxide nanometer material

The invention discloses a method for preparing a comby stannous oxide nanometer material. The method comprises the following steps of: putting stannous chloride dehydrate in a hexadecyl trimethyl ammonium bromide aqueous solution under the condition of stirring by adopting a hydro-thermal synthesis method to obtain a mixed solution; then, dropwise adding a sodium hydroxide aqueous solution to the mixed solution; stirring to obtain a final mixed solution, wherein in the final mixed solution, the molar concentration of the stannous chloride dehydrate is controlled to be between 0.10mol / L and 0.15mol / L, and the molar ratio of the stannous chloride dehydrate to hexadecyl trimethyl ammonium bromide to sodium hydroxide is 1:1:(2-4); putting the final mixed solution in a reaction kettle, wherein the degree of filling is 80-90 percent, and performing a hydrothermal reaction for 12-15h at the temperature of 120-160 DEG C; and performing centrifugation, washing and drying on the obtained product to prepare the comby stannous oxide nanometer material. The prepared comby stannous oxide nanometer material has an even porous structure and can be applied in the aspects of lithium ion battery anode materials, chemical synthesis catalysts and the like. The method disclosed by the invention has the characteristics that the operation is simple, the cost is low, the pollution is low and industrial large-scale production can be easily realized.
Owner:HENAN POLYTECHNIC UNIV

Sulfonated aromatic phosphine oxide polymer containing hydroquinone and preparation method and application thereof

The invention relates to a sulfonated aromatic phosphine oxide polymer containing hydroquinone and a preparation method and application thereof, the structural general formula of the polymer is as follows, wherein M = Li, Na, K, Rb or Cs; when m = 1, the polymer is a homopolymer containing triphenylphosphine oxide and hydroquinone; when m = 0, the polymer is a homopolymer containing triphenylphosphine oxide and sulfonated dihydroxyl monomers; when 0 < m < 1, the polymer is a copolymer containing triphenylphosphine oxide, a sulfonated dihydroxyl monomer and hydroquinone; n is a repeating unit, and n is an integer greater than or equal to 10. Compared with the prior art, a hydroquinone sulfonate structure which is cheap, easy to obtain and easy to treat and purify is introduced into an aromatic phosphine oxide polymer main chain, and the proton exchange membrane material which is good in performance and low in price and has potential application value is prepared on the premise that the phosphine oxide structure is kept.
Owner:SHANGHAI INST OF TECH
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