The invention relates to a high-temperature phase-transitional temperature-sensitive fire-extinguishing gel and a preparation method thereof. Through the physical crosslinking between polyacid with a hydrophilic backbone structure and
polyamine with a hydrophobic backbone structure, the fire-extinguishing gel is in a soluble state at a low temperature and in a
gel state at a high temperature. The fire-extinguishing agent is a low-
viscosity aqueous solution at normal temperature; the
viscosity is gradually increased as the temperature rises, and then the aquagel is formed and adhered on the surface of burning objects, thus the effect of fire-extinguishing is achieved and the
fire behavior is blocked from spreading; after the temperature of the gel is lowered to a certain temperature, the gel is returned to the state of liquid, the residue can be cleaned by using water for flushing, thereby being efficient and environment-friendly. The fire-extinguishing agent provided by the invention has low
viscosity, can be spouted by using the traditional squirt gun; meanwhile, other elements, such as fire-proofing agent,
flame retardant, and the like, can be added to improve the fire-extinguishing performance of the fire-extinguishing agent.