The invention discloses a treatment method of hydrazine
hydrate byproduct
sodium chloride saline water, which comprises the following steps: a, adding an acid into hydrazine
hydrate byproduct
sodium chloride saline water, regulating the pH value of the
saline water to be less than or equal to 4, and adding a homogeneous catalyst into the
saline water; b, fully enabling the heated
saline water to make contact and react with
oxygen; c, adding a homogeneous catalyst into the
saline water after the
primary reaction, adding an acid to adjust the pH value to be less than or equal to 2, and then conducting full contact with
oxygen for reaction; s5, cooling the saline water after the secondary reaction, and removing
gaseous ammonia in the saline water after the secondary reaction through an
ammonia nitrogen separation membrane; and s6, carrying out evaporative
crystallization on the saline water, and then carrying out
solid-liquid separation to obtain a
solid salt product. The method has the advantages that the TOC of the
solid salt product can be controlled to be 10ppm or less, the
ammonia nitrogen can be controlled to be 4ppm or less, and the treatment cost is low. The prepared solid salt can be directly used as a chlor-alkali production
raw material to enter an ionic membrane
electrolytic cell system for use, or is matched with newly purchased raw salt in proportion to enter the ionic membrane
electrolytic cell system for use, and the stable operation of the ionic membrane
electrolytic cell is not influenced.