Semi-dry desulfurization process calcium-based desulfurizing agent and preparation method thereof
A technology for semi-dry desulfurization and desulfurization agent, which is applied in separation methods, chemical instruments and methods, and dispersed particle separation, etc., can solve the problems of difficult promotion, complicated preparation process, and high price of desulfurization agent, and achieves high economic and social Effectiveness, high stability, high digestive activity and effect of desulfurization efficiency
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Embodiment 1
[0028] A calcium-based desulfurizer for a semi-dry desulfurization process, the preparation method of which comprises the steps of:
[0029] 1) Raw materials are weighed: the mass percentages of each raw material are: quicklime powder 9.5%, lime kiln dust removal powder 15% and lime kiln sieve material 75%, admixture (calcium chloride) 0.5%;
[0030] 2) Mix the weighed raw materials evenly, so that the gradation relationship of particle size d in the obtained mixture is controlled at: d<0.1mm 15-25%, 0.2≤d<0.3mm 25-45%, 0.8≤d<1mm 30% to 60%, wherein each particle size range is based on the mass percentage of calcium oxide remaining in each sieve; that is, the calcium-based desulfurizer for the semi-dry desulfurization process (wherein the content of calcium oxide in the calcium-based desulfurizer is 85.2%).
[0031] The obtained calcium-based desulfurizer is digested with water, and the concentration of the obtained slurry is controlled to be 18wt%, the initial water temperatu...
Embodiment 2
[0034] A calcium-based desulfurizer for a semi-dry desulfurization process, the preparation method of which comprises the steps of:
[0035] 1) Raw materials are weighed: the mass percentages of each raw material are: quicklime powder 14%, lime kiln dust removal powder 10% and lime kiln sieve material 75%, admixture (calcium chloride) 1%;
[0036] 2) Mix the weighed raw materials evenly, so that the gradation relationship of particle size d in the obtained mixture is controlled at: 0.1≤d<0.2mm 15-25%, 0.3≤d<0.4mm 25-45%, 0.8≤d <1mm 30-60%, wherein each particle size range is calculated by the mass percentage of calcium oxide remaining in each sieve; that is, the calcium-based desulfurizer for the semi-dry desulfurization process is obtained. (wherein the content of calcium oxide in the calcium-based desulfurizer is 83.4%).
[0037]The obtained calcium-based desulfurizer is digested with water, the concentration of the obtained slurry is controlled to 20wt%, the initial water ...
Embodiment 3
[0040] A calcium-based desulfurizer for a semi-dry desulfurization process, the preparation method of which comprises the steps of:
[0041] 1) Raw materials are weighed: the mass percentages of each raw material are: quicklime powder 20%, lime kiln dust removal powder 18% and lime kiln sieve material 60%, admixture (calcium fluoride) 2%;
[0042] 2) Mix the weighed raw materials evenly, so that the gradation relationship of particle size d in the obtained mixture is controlled at: 0≤d<0.1mm 15-25%, 0.5≤d<0.8mm 25-45%, 1≤d <2mm 30-60%, wherein each particle size range is calculated by the mass percentage of calcium oxide remaining in each sieve; that is, the calcium-based desulfurizer for the semi-dry desulfurization process is obtained. (wherein the content of calcium oxide in the calcium-based desulfurizer is 89.3%).
[0043] The obtained calcium-based desulfurizer is digested with water, the concentration of the obtained slurry is controlled to be 22wt%, the initial water ...
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