A preparation method for acidic silica
sol in-situ modified
acrylate emulsion includes the steps: firstly, diluting acidic silica
sol with deionized water prior to adding small molecular
alcohol, and then adding organo-
siloxane with mixing to obtain modified acidic silica
sol; then, utilizing the modified acidic silica sol, emulsifier, nuclear-layer monomers, deionized water and
sodium bicarbonate to prepare seed pre-
emulsion by means of pre-emulsification, adding the seed pre-
emulsion into a reactor, heating up and adding initiator to initiate
polymerization so that seed emulsion is prepared; and finally, adding emulsifier, shell monomers, initiator and deionized water into the reactor to prepare pre-emulsion by means of pre-emulsification, adding the pre-emulsion into the seed emulsion, replenishing initiator to hold, filtering after cooling to the normal temperature, and adjusting a pH (potential of
hydrogen) value so that the modified
acrylate emulsion is prepared. By the aid of the method, secondary dispersion of nano silica is avoided, stability of the emulsion is enhanced, and
hardness, resistance to
ultraviolet ageing and resistance to high temperature of an emulsion
coating film are enhanced.