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2279 results about "Nylon 6" patented technology

Nylon 6 or polycaprolactam is a polymer developed by Paul Schlack at IG Farben to reproduce the properties of nylon 6,6 without violating the patent on its production. (Around the same time, Kohei Hoshino at Toray also succeeded in synthesizing nylon 6.) It is a semicrystalline polyamide. Unlike most other nylons, nylon 6 is not a condensation polymer, but instead is formed by ring-opening polymerization; this makes it a special case in the comparison between condensation and addition polymers. Its competition with nylon 6,6 and the example it set have also shaped the economics of the synthetic fiber industry. It is sold under numerous trade names including Perlon (Germany), Dederon (former East Germany), Nylatron, Capron, Ultramid, Akulon, Kapron (former Soviet Union and satellite states), and Durethan.

Nylon 6 polymerization method and direct spinning method of melt of polymer obtained with nylon 6 polymerization method

The invention relates a nylon 6 polymerization method and a direct spinning method of a melt of a polymer obtained with the nylon 6 polymerization method. A polyamide 6 prepolymer is prepared at the low temperature, the content of oligomers in the melt is controlled in advance, polymerization is completed before a large quantity of cyclic oligomers are generated with a condensation polymerization dynamic strengthening method, a nylon 6 polymer melt with certain molecular weight is acquired, the content of extracts in the product is smaller than or equal to 1.5 wt%, and the content of cyclic dipolymers is smaller than or equal to 0.2wt%; then, direct melt spinning forming is performed after condensation polymerization dynamic strengthening ends. The process is simple, energy consumption is further reduced while the utilization rate of caprolactam is increased, the obtained melt can be directly used for melt spinning, high-capacity large-scale production is easy to realize, a modifier can be added in the polymerization process, flexible production of nylon 6 is realized, and the nylon 6 can be applied to fibers for clothes, industrial filaments, engineering plastics and other fields.
Owner:ZHEJIANG HENGYI PETROCHEMICAL RES INST CO LTD

Preparation method of graphene modified nylon 6 fiber

The invention relates to a preparation method of a graphene modified nylon 6 fiber and belongs to the technical field of a functional fiber material. The preparation method comprises the following steps of: carrying out carboxylation and acylating chlorination treatment on graphene; then carrying out diamine treatment to obtain graphene oxide with an active amino on the surface; carrying out polymerization reaction by utilizing the aminated graphene and caprolactam through an initiator 6-aminocaproic acid to prepare a modified nylon 6 melt of the graphene; and carrying out spinning and stretching through a fusion and spinning process to obtain the graphene modified nylon 6 fiber. The technical scheme of the invention utilizes aminated graphene enhanced 6 to improve the interface bonding strength with a base resin, so as to be good for improving the whole performance of the graphene modified nylon 6 fiber. A fiber material prepared by the preparation method provided by the invention can be widely applied to the technical fields of aerospace, cars and ships, communication and transportation, mechano-electronics and the like.
Owner:SUZHOU UNIV

A high flame retardant high thermal conductivity composite material component and its manufacturing method

The invention relates to a high-molecular composite material having performances of high heat conduction and high flame retardation, the invention is characterized in that the composite material does not contain any halogen or a non environmentally-friendly heavy metal fire retardant, the flame resistance is capable of reaching a UL94 V0 standard, simultaneously, the composite material has good heat conducting performance, the heat conduction coefficient is more than 0.5 W / m. DEG C. The composite material provided in the invention has good injection moulding performance, extruding performance and hot pressing performance. The composite material comprises the following basic components: 1) one or a plurality of metal hydroxides, such as aluminum hydroxide, magnesium hydroxide, zinc hydroxide and the like, wherein the weight content is 10-70%, 2) about 0.2%-60% of the weight content of expandable graphite flaky powder, the lamina size is more than 10 um, and the expandable coefficient is more than or equal to 20 times; 3) 15%-70% of the weight content of matrix resins, such as epoxy resin, organic silicone resin, phenolic resin, thermosetting polyester resin and thermoplastic resins of nylon 6, nylon 66, PBT, PP, HDP and the like. The composite material component of the invention can be directly used for radiators such as LED, electric appliances and electronic components, the heat can be radiated into colder environment so that the operating temperature of the electronic device can be reduced.
Owner:HEFU NEW MATERIAL TECH WUXI

Halogen free flame retardant nylon 6 composite with high CTI value and preparation method thereof

The invention discloses a halogen free flame retardant nylon 6 composite with high CTI value and a preparation method thereof. The composite comprises the following components by mass percent: 643.5-68.8wt.% of nylon, 10-12wt.% of fire retardant, 7-19wt.% of fire retardant synergetic inorganic packing, 8-12% wt.% of toughening agent, 1-3wt.% of bulking agent, 5-10% wt.% of enhance inorganic filler and 0.2-0.5wt.% of anti-oxygen which are prepared into the compound by a high speed premixing dispersing primary extrusion processing. The disclosed composite has as high as 550V CTI value and UL 94V-0 level excellent fire resistance; simultaneously, the polymer has good mechanical property by a comprehensive modified technique, wherein the tensile strength reaches 70.5Mpa, the bending strength reaches 90.7MPa and the impacting strength of a gap reaches 28.1kJ/m2. The invention solves the problem that the flaming resistant and high CTI value are difficult to satisfy simultaneously; the inventive 6 nylon compound is very suitable for preparing a low-pressure vacuum contactor, a transformer coil framework, a high-temperature resistant relay, a breaker, a high voltage electrical apparatus, a handle and a thin wall electronic and electrical appliance elements, and the like.
Owner:BEIJING UNIV OF CHEM TECH

Flame-retardant PP/nylon corrugated tube composite material and preparation method thereof

The invention relates to a corrugated tube material and particularly discloses a flame-retardant PP (Polypropylene) / nylon corrugated tube composite material and a preparation method thereof, aiming to overcome the shortcomings in the prior art that the mechanical property of the PP corrugated tube is bad, the nylon corrugated tube is not flame-retardant, the stability is bad, and the service lifeis short. The material disclosed by the invention comprises the following substances by weight percentage: 47-75 of PP, 3-40 of nylon, 5-30 of flame retardant, 5-20 of compatilizer, 1-40 of flexibilizer, 0-10 of filling master batches, 0.2-1.5 of heat stabilizer, and 0.2-1.5 of processing agent. The preparation method comprises the steps as follows: the filling master batches are firstly preparedand then added into a twin-screw extruder to melt and mix with other materials, and pelletings are extruded out to prepare the flame-retardant PP / nylon composite material. The invention has the advantages of favorable flame-retardant property, excellent high-temperature resistance, friction resistance, chemical corrosion resistance, long service life, high surface glossiness, high electrical insulativity, simple manufacturing technology, and low cost.
Owner:SHANGHAI KINGFA SCI & TECH +1

Nylon 6/graphene nanometer composite material with high thermal conductivity and preparation method thereof

The invention relates to a nylon 6 / graphene nanometer composite material with high thermal conductivity and a preparation method thereof. The composite material is composed of a nylon 6 matrix and nanometer graphene and is prepared by carrying out in situ polymerization and melt blending and banburying on obtained master batches and pure nylon 6. The nanometer graphene oxide adopted in the preparation method has a high radius-thickness ratio, a small amount of nanometer graphene oxide is added and is thermally reduced to form heat-conducting master batches, and an effective graphene heat conducting path can be formed effectively in the nylon 6. The small amount of nanometer graphene oxide heat conducting fillers and the master batches are added into the pure nylon 6 to be mixed and compounded so as to keep the good mechanical properties of the nylon 6 in the heat-conducting composite material. The nylon 6 / graphene nanometer composite material with high thermal conductivity, provided by the invention, is excellent in heat conducting property, simple in preparation process and low in cost, thereby being capable of being widely applied in the field of heat dissipation of automobiles, computers, LEDs (Light Emitting Diode), etc.
Owner:SHANGHAI UNIV

High-fluidity halogen-free flame retardant reinforced nylon composite material and preparation method thereof

The invention discloses a high-fluidity halogen-free flame retardant reinforced nylon composite material and a preparation method thereof. According to the invention, high-fluidity nylon resin containing chain structural nylon 6 is adopted as matrix resin; 4.9 to 29.5 parts of halogen-free flame retardant and 0.1 to 0.5 part of antioxidant are added in a mixing machine for evenly mixing; the obtained mixture is melted and extruded through a screw extruder; a reinforcement component is added in the extruding process; and finally, a novel halogen-free flame retardant reinforced nylon composite material of the high-fluidity halogen-free flame retardant reinforced nylon composite material is obtained through drawing, cooling and pelletizing. The flame retardant reinforced nylon composite material has the characteristics of high melt fluidity, good environmental friendliness and flame retardance, good electric performance, excellent mechanical performance and the like; and obtained products have excellent surface performance, low warpage and high smoothness. The material can be widely applied in the field of electric plastic parts, such as casings, breakers, wire connection boxes, socket switches and the like of semiconductor devices such as IGBT (Insulated Gate Bipolar Transistor) and the like.
Owner:株洲时代工程塑料实业有限公司

Laminated packaging material and method for producing the same

This invention relates to the laminated material for food packaging, and its manufacturing process. The laminated material (10) consists of the quality keeping intermediate layer (12) laminated inside the paper core layer (11) and the core layer and the heat sealable innermost layer (13). The quality keeping intermediate layer comprises of an extrusion coatable blend polymer consisting of polymer component A 50-95% of nylon-MXD6 or EVOH and, polymer component B 5-50% of nylon 6, nylon 6, the blends or PET. The quality keeping intermediate layer is extruded and laminated directly in the core layer, the innermost layer contains at least the linear low density polyethylene which has a narrow molecular weight distribution, and has the properties parameter of mean density of 0.910-0.925, 100-122 degrees C. peak melting point, melt flow index of 5-20, swelling ratio (SR) of 1.4-1.6, and 5-50 micrometer layer thickness.The hardness, production efficiency, and cost performance of the barrier packaging container formed by the packaging material are improved.
Owner:TETRA LAVAL HLDG & FINANCE SA

Processing method of high-strength low-shrinkage nylon 6 fine denier filament

The invention discloses a processing method of a high-strength low-shrinkage nylon 6 fine denier filament, belonging to the technical field of nylon filament processing. The method comprises the following steps: preparing materials: adding the nylon 6 slices into a bin of nitrogen protective gas to obtain a material to be melted; melting: introducing the material to be melted into a screw extruder for melting to obtain a melt; forming: introducing the melt from the upper part of a spinning box, and ejecting from a spinneret orifice of a spinneret plate to obtain a filament bundle; cooling: introducing the filament bundle into a slow-cooling area for slow cooling, forming through side-blowing air cooling, and further cooling through a channel; oiling and pre-interlacing: oiling the cooling-formed filament bundle through an oil lip or oil wheel, and pre-interlacing; drafting: feeding the filament bundle to be drafted through a feeding roller, drafting through a heat roller, and then performing relax-type setting to obtain the drafting-set filament; and re-interlacing and re-oiling: re-interlacing and re-oiling the drafting-set filament before packaging to obtain the high-strength low-shrinkage nylon 6 fine denier filament. The method can adapt to different purposes of products, and can be applied to the occasions having rigorous requirements on the breaking strength and dry heat shrinkage.
Owner:CHANGSHU POLYESTER

High-flowability polyamide based halogen-free flame-retardant heat-conducting composite material and preparation method thereof

The invention discloses a high-flowability polyamide halogen-free flame-retardant heat-conducting composite material and a preparation method thereof. A novel halogen-free flame-retardant heat-conducting composite material is prepared by using high-flowability nylon 6 resin with a branch chain structure as a base body, adding additives such as heat-conducting fillers, a halogen-free flame retardant, an antioxidant and a coupler, and preparing the material through a double-screw melt blending technology. The halogen-free flame-retardant heat-conducting composite material has the characteristics of good heat conductivity, high melt flowability, good environment-friendly and flame-retardant performances, excellent insulation and mechanical comprehensive performances and the like; an obtained product is high in heat-radiating speed, high in strength, low in warping degree and resistant to high temperature and ageing; the composite material can be widely applied to the field of electric plastic parts with higher heat-radiating requirements such as locomotive compartment illumination lamp covers, auto and civil LED heat radiators, household appliance motor shells, notebook power, micro-projector shells, transformer coil frameworks and the like.
Owner:株洲时代工程塑料制品有限责任公司

Heat-conducting, wear-resistant and insulated nylon 6 composite material and preparation method thereof

InactiveCN103602060APolymer scienceHeat conducting
The invention relates to a heat-conducting, wear-resistant and insulated nylon 6 composite material and a preparation method thereof. The material is composed of the following raw materials in percentage by weight: 20-50% of PA 6, 10-30% of fibrous heat-conducting fillers, 15-30% of insulated heat-conducting powder A, 5-10% of insulated heat-conducting powder B, 5-15% of heat-conducting wear-resistant powder, 0.75-1.5% of coupling agent, 3-10% of compatibilizer, 0.2-0.5% of antioxidant and 0.2-0.5% of lubricant. According to the heat-conducting, wear-resistant and insulated nylon 6 composite material provided by the invention, heat-conducting fillers with different particle sizes, different shapes and different draw ratios are compounded so that the fillers are more uniformly distributed in a plastic matrix so as to form a heat-conducting network more easily. Since a low-feeding high-shearing extrusion process is used in the invention, an extruder is at a hungry state to achieve an effect of dispersing the fillers more uniformly. When the fibrous heat conducting fillers are added, a single screw extruder is used, so that the fibers can be sheared into smaller size, the damage is smaller, and meanwhile, the fillers are dispersed more uniformly by extruding the fillers by the extruder for the second time; and the heat-conducting, wear-resistant and insulated nylon 6 composite material provided by the invention has the advantages of good heat conducting effect, excellent wear resistance, easy workability, etc.
Owner:SHANGHAI UNIV

Warpage resistance nylon 6 composite material for vehicle air conditioning air door and preparation method thereof

The invention discloses a warpage resistance nylon 6 composite material for a vehicle air conditioning air door and a preparation method thereof. The composite material is composed of nylon 6 chips, fiberglass, glass microballoons, compatilizer, antioxidizer, a coupling agent and a lubricating agent. The preparation method includes the following steps: (1) after being uniformly mixed, the nylon 6 chips, the compatilizer, the antioxidizer, the coupling agent and the lubricating agent are added into a double screw extruder on the first segment of a barrel, the glass microballoons are added by a side feeding machine on the fourth segment of the barrel, and the fiberglass is added by the side feeding machine on the sixth segment of the barrel; and (2) after being extruded outside, the prepared particles are dried and cooled, and finally the warpage resistance nylon 6 composite material for the vehicle air conditioning air door can be obtained. The warpage resistance nylon 6 composite material prepared by the invention has the advantages of extremely high flexural modulus, high fluidity and favorable dimension stability, solves the problem of warpage of a large finished piece caused by material shrinkage, and guarantees the assembly of the finished piece.
Owner:合诚技术股份有限公司

Method for preparing nylon 6/graphite oxide nanocomposite

The invention relates to a method for preparing a nylon 6 / graphite oxide nanocomposite. In the method, caprolactam is adopted for in situ hydrolysis and ring-opening polymerization to prepare the nylon 6 / graphite oxide nanocomposite, so that caprolactam monomers are easy to perform in-situ intercalative polymerization to dissociate a graphite oxide lamella, and the dispersing uniformity of the graphite oxide lamella in a polymer substrate is improved; and the composite prepared has better conductivity and high-efficiency flame retardancy. The nylon 6 substrate is converted from an insulator to a semiconductor and the flame retardant rating can reach V-0 rating of a UL94 standard, and the integral good mechanical property of the material per se is maintained simultaneously. The method has the advantage of simple and effective process; the conductivity and flame retardancy of the obtained composite are obviously improved; the material has good secondary-working character; an additive graphite oxide does not pollute the environment; and the nylon 6 / graphite oxide nanocomposite has wide application range.
Owner:SHANGHAI GENIUS ADVANCED MATERIAL (GRP) CO LTD
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