The invention discloses a bromine-free bread and a production method thereof, which is prepared by compounding enzyme preparation, emulsifier, vitamin C, calcium iodide, thickener and filler. In this formula, vitamin C and calcium iodide are used to replace potassium bromate, which reduces the potential safety hazard in production, and at the same time, there is no harm to the human body caused by residual potassium bromate in bread. The invention can effectively improve the operability of the dough, improve the softness of the bread during bread making, increase the nutritional value of the bread, and supplement the intake of human vitamins and iodine.