The invention discloses a
silver nano column cluster array, as well as a preparation method and application thereof. The
silver nano column cluster array comprises the
silver nano column clusters covering a
gold film, wherein the silver nano column clusters constituting the silver nano column cluster array comprises more than 20 silver nano columns; the
diameter and length of each silver nano column are 5-75 nm and 750-850 nm respectively, the distance between the centers of the roots of two columns is 130-170 nm, and the top ends of the more than 20 columns are gathered. The preparation method comprises the following steps: a
monolayer crystal template is moved to the surface of a through-hole
alumina template, the
gold film is sputtered on the
monolayer crystal template, then, the
monolayer crystal template is placed in a silver
electrolyte, the monolayer crystal template is removed after the silver nano columns is subjected to electro-deposition, after the
gold film is sputtered on one surface, covering the gold film, of the
alumina template, the
alumina template is dissolved away, and then the gold film on which the silver nano column cluster array is placed is dried to prepare the objective product, wherein one surface of the alumina template is coated with the gold film, and the silver nano columns are placed in the through holes of the alumina template. The silver nano column cluster array can be used as the active substrate of surface reinforced
raman scattering, and a
laser Raman
spectrometer is utilized to measure
polychlorinated biphenyl-3 attached thereon or measure the content of
parathion-methyl in an organophosphorus
pesticide or the content of 2, 4-D in an organo-
chlorine pesticide.