The invention relates to a process method for circularly utilizing waste water produced by butadiene preparation through
butene oxidative
dehydrogenation and belongs to the technical field of
chemical industry. The process method is characterized in that: firstly, most of the waste water is sent to an exhaust-heat
recovery boiler for use after most organic matters in the waste water discharged from a water-cooling acid rinsing
tower are deprived through a waste water
distillation tower, and desalted water replenishing of the exhaust-heat
recovery boiler is replaced; secondly, partial waste water returns an
aldehyde rinsing
tower for reusing after most aldehydes in the waste water discharged from the
aldehyde rinsing tower are deprived through a blowdown tower, and desalted water using quantity of the
aldehyde rinsing tower is reduced; and thirdly, low temperature condensation is carried out for
tail gas containing acid and aldehyde, organic matters condensate liquid in the
tail gas is recycled, and loads of a
waste gas processing system is lightened. Compared with the prior art, a waste water classifying treatment and cyclic utilization process of the process method effectively reduces water replenishing quantity of a technical process, greatly reduces
effluent quantity of the waste water simultaneously, reduces a
chemical oxygen demand (COD) concentration of discharged
sewage and an
organic content in discharged gas, and has advantages of being economic, environment-friendly and the like.