The invention relates to a
flue gas desulfurization process used for a
zinc smelting system. The process comprises the following steps: preparing ZnO
slurry: after
zinc scum is casted, performing ballmilling, separating
metal zinc, performing defluorination and dechlorination on the scum
powder until the
fluorine content is not more than 0.1% and the
chlorine content is not more than 0.3% in thezinc scum, performing slurrying in a slurrying tank, allowing the obtained
slurry to enter a vertical mill process, and further
grinding the zinc
oxide to form ZnO
slurry; performing first-stage desulfurization: spraying a prepared ZnO slurry into a first-stage absorption
tower, and reacting the ZnO slurry with
sulfur dioxide in washed
zinc smelting system flue gas; performing second-stage desulfurization, and performing third-stage desulfurization. The process is characterized in that zinc
sulfite slurry formed after the reaction is concentrated, the supernatant is discharged into an aerationoxidation tank, after the bottom
stream is filtered, the filtrate is discharged into the
aeration oxidation tank, the solution obtained by oxidation in the
aeration oxidation tank returns to the slurrying tank in the ZnO slurry preparation part for recycling, after a
zinc ion concentration in the solution reaches 150 g / L, the material is sent to a zinc purification
system for further treatment without deposition, and the filter residues are sent to a zinc
sulfite bin to be treated together with other zinc-containing materials for comprehensive
recovery of zinc. The process provided by the invention has no harmful
waste gas, waste residues or waste water.